The thermodynamic properties of rare-earth metal binuclear acetates and pivalates
Zh V Dobrokhotova
1
,
I.G. Fomina
1
,
M. A. Kiskin
1
,
M. A. Bykov
2
,
G V Belov
2
,
V. M. Novotortsev
1
Тип публикации: Journal Article
Дата публикации: 2006-03-20
scimago Q4
wos Q4
БС3
SJR: 0.204
CiteScore: 1.2
Impact factor: 0.8
ISSN: 00360244, 1531863X
Physical and Theoretical Chemistry
Краткое описание
The temperature dependence of the heat capacities of binuclear acetates M2(η1,η2-OOCCH3)2(η2-OOCCH3)4(H2O)4 · xH2O (M = La(1), Sm(2), Eu(3), and Tm(4)) (113−330 K); pivalates M2(μ2-OOCCMe3)4(OOCCMe3)2(HOOCCMe3)4·HOOCCMe3 (M=La(5), Sm(6), and Eu(7)) (113−320 K); and intermediate products of their thermal decomposition M2(OOCCH3)6(113–330 K) and M2(OOCCMe3)6 (113–500 K) and enthalpy changes at particular decomposition stages were determined by differential scanning calorimetry. The composition of the solid phase formed in decomposition was determined experimentally. The complete set of thermodynamic data was obtained, including C p (T), S°(298), Δf H°(298), and Δf G°(298), for binuclear lanthanide acetates and pivalates specified above. The composition of the gas phase formed in decomposition was determined, which allowed us to suggest a resultant scheme of the thermal destruction of pivalates. The reliability of this scheme was demonstrated.
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Dobrokhotova Z. V. et al. The thermodynamic properties of rare-earth metal binuclear acetates and pivalates // Russian Journal of Physical Chemistry A. 2006. Vol. 80. No. 3. pp. 323-329.
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Dobrokhotova Z. V., Fomina I., Kiskin M. A., Bykov M. A., Belov G. V., Novotortsev V. M. The thermodynamic properties of rare-earth metal binuclear acetates and pivalates // Russian Journal of Physical Chemistry A. 2006. Vol. 80. No. 3. pp. 323-329.
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TY - JOUR
DO - 10.1134/S0036024406030034
UR - https://doi.org/10.1134/S0036024406030034
TI - The thermodynamic properties of rare-earth metal binuclear acetates and pivalates
T2 - Russian Journal of Physical Chemistry A
AU - Dobrokhotova, Zh V
AU - Fomina, I.G.
AU - Kiskin, M. A.
AU - Bykov, M. A.
AU - Belov, G V
AU - Novotortsev, V. M.
PY - 2006
DA - 2006/03/20
PB - Pleiades Publishing
SP - 323-329
IS - 3
VL - 80
SN - 0036-0244
SN - 1531-863X
ER -
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@article{2006_Dobrokhotova,
author = {Zh V Dobrokhotova and I.G. Fomina and M. A. Kiskin and M. A. Bykov and G V Belov and V. M. Novotortsev},
title = {The thermodynamic properties of rare-earth metal binuclear acetates and pivalates},
journal = {Russian Journal of Physical Chemistry A},
year = {2006},
volume = {80},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S0036024406030034},
number = {3},
pages = {323--329},
doi = {10.1134/S0036024406030034}
}
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Dobrokhotova, Zh V., et al. “The thermodynamic properties of rare-earth metal binuclear acetates and pivalates.” Russian Journal of Physical Chemistry A, vol. 80, no. 3, Mar. 2006, pp. 323-329. https://doi.org/10.1134/S0036024406030034.