volume 82 issue 7 pages 1164-1169

The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations

Publication typeJournal Article
Publication date2008-07-01
scimago Q4
wos Q4
SJR0.204
CiteScore1.2
Impact factor0.8
ISSN00360244, 1531863X
Physical and Theoretical Chemistry
Abstract
The molecular structure of the isomer 4348 (C 2v ) of fullerene C66, which does not obey the rule of isolated pentagons, is analyzed. Data on the distribution of single, double, and delocalized bonds in this molecule were obtained for the first time. Quantum-chemical (DFT) calculations showed that the hypothetical C66 molecule was a biradical, which was the reason for its instability. In metallofullerene Sc2@C66, the main changes in bond lengths and electron density transfer from scandium atoms to the carbon shell of fullerene occurred in pentalene substructures and conjugated π bond chains.
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Khamatgalimov A. R., Kovalenko V. I. The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations // Russian Journal of Physical Chemistry A. 2008. Vol. 82. No. 7. pp. 1164-1169.
GOST all authors (up to 50) Copy
Khamatgalimov A. R., Kovalenko V. I. The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations // Russian Journal of Physical Chemistry A. 2008. Vol. 82. No. 7. pp. 1164-1169.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0036024408070194
UR - https://doi.org/10.1134/S0036024408070194
TI - The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations
T2 - Russian Journal of Physical Chemistry A
AU - Khamatgalimov, A R
AU - Kovalenko, V. I.
PY - 2008
DA - 2008/07/01
PB - Pleiades Publishing
SP - 1164-1169
IS - 7
VL - 82
SN - 0036-0244
SN - 1531-863X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2008_Khamatgalimov,
author = {A R Khamatgalimov and V. I. Kovalenko},
title = {The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations},
journal = {Russian Journal of Physical Chemistry A},
year = {2008},
volume = {82},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0036024408070194},
number = {7},
pages = {1164--1169},
doi = {10.1134/S0036024408070194}
}
MLA
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Khamatgalimov, A. R., and V. I. Kovalenko. “The structure of fullerene C66, which does not obey the rule of isolated pentagons, and endohedral metallofullerene Sc2@C66: Quantum-chemical calculations.” Russian Journal of Physical Chemistry A, vol. 82, no. 7, Jul. 2008, pp. 1164-1169. https://doi.org/10.1134/S0036024408070194.