Russian Journal of Physical Chemistry A, volume 82, issue 12, pages 2030-2034

The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions

Makarova S P ¹

Rumyantsev E V ¹

Antina E V ²

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Ivanovo State University of Chemical Technology, Ivanovo, Russia |

Institute of the Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia |

Publication type: Journal Article

Publication date: 2008-11-27

Pleiades Publishing

Journal: Russian Journal of Physical Chemistry A

Quartile SCImago

Quartile WOS

Impact factor: 0.7

ISSN: 00360244, 1531863X

DOI: 10.1134/S0036024408120108

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Physical and Theoretical Chemistry

Abstract

The spectral and calorimetric data on complex formation between alkyl substituted a,c-biladiene and Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) acetates in dimethylformamide are discussed. The stability of mononuclear biladiene chelates was shown to be determined by steric factors characterizing the formation of coordination polyhedra with the tetradentate ligand. The thermodynamic characteristics of the differential polychelate effect caused by the replacement of the bidentate dipyrrolylmetene ligand with the tetradentate biladiene anion in mononuclear zinc(II) complexes were estimated. The results showed that the largest contribution to the polychelate effect was made by the enthalpy component of the Gibbs energy.

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Citations by journals

	1
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 33.33% Russian Journal of Inorganic Chemistry 1 publication, 33.33%
Dyes and Pigments	Dyes and Pigments, 1, 33.33% Dyes and Pigments 1 publication, 33.33%
Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya	Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya, 1, 33.33% Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya 1 publication, 33.33%
	1

Citations by publishers

	1
Pleiades Publishing	Pleiades Publishing, 1, 33.33% Pleiades Publishing 1 publication, 33.33%
Elsevier	Elsevier, 1, 33.33% Elsevier 1 publication, 33.33%
Ivanovo State University of Chemistry and Technology	Ivanovo State University of Chemistry and Technology, 1, 33.33% Ivanovo State University of Chemistry and Technology 1 publication, 33.33%
	1

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Makarova S. P., Rumyantsev E. V., Antina E. V. The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions // Russian Journal of Physical Chemistry A. 2008. Vol. 82. No. 12. pp. 2030-2034.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S0036024408120108

UR - https://doi.org/10.1134%2FS0036024408120108

TI - The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions

T2 - Russian Journal of Physical Chemistry A

AU - Makarova, S P

AU - Rumyantsev, E V

AU - Antina, E V

PY - 2008

DA - 2008/11/27 00:00:00

PB - Pleiades Publishing

SP - 2030-2034

IS - 12

VL - 82

SN - 0036-0244

SN - 1531-863X

ER -

BibTex |

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BibTex Copy

@article{2008_Makarova,

author = {S P Makarova and E V Rumyantsev and E V Antina},

title = {The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions},

journal = {Russian Journal of Physical Chemistry A},

year = {2008},

volume = {82},

publisher = {Pleiades Publishing},

month = {nov},

url = {https://doi.org/10.1134%2FS0036024408120108},

number = {12},

pages = {2030--2034},

doi = {10.1134/S0036024408120108}

}

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Makarova, S. P., et al. “The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions.” Russian Journal of Physical Chemistry A, vol. 82, no. 12, Nov. 2008, pp. 2030-2034. https://doi.org/10.1134%2FS0036024408120108.

Found error?

Publisher

Pleiades Publishing

Journal

Russian Journal of Physical Chemistry A

Quartile SCImago

Quartile WOS

Impact factor

0.7

ISSN

00360244 (Print)
1531863X (Electronic)

Labs

Chemistry and molecular photonics of dipyrromethene dyes and phosphors

Profiles

Antina, Elena E V