The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions
Тип публикации: Journal Article
Дата публикации: 2008-11-27
scimago Q4
wos Q4
БС3
SJR: 0.204
CiteScore: 1.2
Impact factor: 0.8
ISSN: 00360244, 1531863X
Physical and Theoretical Chemistry
Краткое описание
The spectral and calorimetric data on complex formation between alkyl substituted a,c-biladiene and Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) acetates in dimethylformamide are discussed. The stability of mononuclear biladiene chelates was shown to be determined by steric factors characterizing the formation of coordination polyhedra with the tetradentate ligand. The thermodynamic characteristics of the differential polychelate effect caused by the replacement of the bidentate dipyrrolylmetene ligand with the tetradentate biladiene anion in mononuclear zinc(II) complexes were estimated. The results showed that the largest contribution to the polychelate effect was made by the enthalpy component of the Gibbs energy.
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Makarova S. P., Rumyantsev E. V., Antina E. V. The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions // Russian Journal of Physical Chemistry A. 2008. Vol. 82. No. 12. pp. 2030-2034.
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Makarova S. P., Rumyantsev E. V., Antina E. V. The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions // Russian Journal of Physical Chemistry A. 2008. Vol. 82. No. 12. pp. 2030-2034.
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TY - JOUR
DO - 10.1134/S0036024408120108
UR - https://doi.org/10.1134/S0036024408120108
TI - The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions
T2 - Russian Journal of Physical Chemistry A
AU - Makarova, S P
AU - Rumyantsev, E V
AU - Antina, E V
PY - 2008
DA - 2008/11/27
PB - Pleiades Publishing
SP - 2030-2034
IS - 12
VL - 82
SN - 0036-0244
SN - 1531-863X
ER -
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@article{2008_Makarova,
author = {S P Makarova and E V Rumyantsev and E V Antina},
title = {The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions},
journal = {Russian Journal of Physical Chemistry A},
year = {2008},
volume = {82},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0036024408120108},
number = {12},
pages = {2030--2034},
doi = {10.1134/S0036024408120108}
}
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Makarova, S. P., et al. “The thermodynamic characteristics of formation of mono-and binuclear biladiene Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) chelates in dimethylformamide solutions.” Russian Journal of Physical Chemistry A, vol. 82, no. 12, Nov. 2008, pp. 2030-2034. https://doi.org/10.1134/S0036024408120108.
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