Russian Journal of Physical Chemistry A

, volume 86 , issue 7 , pages 1048-1052

The kinetics of oxidation of bilirubin and ascorbic acid in solution

A. V. Solomonov ¹

E V Rumyantsev ¹

B A Kochergin ¹

E V Antina ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Ivanovo State University of Chemical Technology, Ivanovo, Russia |

Krestov Institute of the Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia |

Publication type: Journal Article

Publication date: 2012-05-24

Pleiades Publishing

Russian Journal of Physical Chemistry A

scimago Q4

wos Q4

SJR: 0.204

CiteScore: 1.2

Impact factor: 0.8

ISSN: 00360244, 1531863X

DOI: 10.1134/S0036024412070266

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Physical and Theoretical Chemistry

Abstract

The results of a comparative study of the oxidation of bilirubin, ascorbic acid, and their mixture in aqueous solutions under the action of air oxygen and hydrogen peroxide are presented. The observed and true rate constants for the oxidation reactions were determined. It was shown that the oxidation of tetrapyrrole pigment occurred under these conditions bypassing the stage of biliverdin formation to monopyrrole products. Simultaneous oxidation of bilirubin and ascorbic acid was shown to be accompanied by the inhibition of ascorbic acid oxidation by bilirubin, whereas ascorbic acid itself activated the oxidation of bilirubin.

Found

2 citations

Berezin Mikhail

DSc in Chemistry, professor

159 publications, 1 627 citations

h-index: 19

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

Research interests

Porphyrins

Synthesis

2 citations

Antina Elena

DSc in Chemistry

207 publications, 2 270 citations

h-index: 22

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences

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Solomonov A. V. et al. The kinetics of oxidation of bilirubin and ascorbic acid in solution // Russian Journal of Physical Chemistry A. 2012. Vol. 86. No. 7. pp. 1048-1052.

GOST all authors (up to 50) Copy

Solomonov A. V., Rumyantsev E. V., Kochergin B. A., Antina E. V. The kinetics of oxidation of bilirubin and ascorbic acid in solution // Russian Journal of Physical Chemistry A. 2012. Vol. 86. No. 7. pp. 1048-1052.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S0036024412070266

UR - https://doi.org/10.1134/S0036024412070266

TI - The kinetics of oxidation of bilirubin and ascorbic acid in solution

T2 - Russian Journal of Physical Chemistry A

AU - Solomonov, A. V.

AU - Rumyantsev, E V

AU - Kochergin, B A

AU - Antina, E V

PY - 2012

DA - 2012/05/24

PB - Pleiades Publishing

SP - 1048-1052

IS - 7

VL - 86

SN - 0036-0244

SN - 1531-863X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2012_Solomonov,

author = {A. V. Solomonov and E V Rumyantsev and B A Kochergin and E V Antina},

title = {The kinetics of oxidation of bilirubin and ascorbic acid in solution},

journal = {Russian Journal of Physical Chemistry A},

year = {2012},

volume = {86},

publisher = {Pleiades Publishing},

month = {may},

url = {https://doi.org/10.1134/S0036024412070266},

number = {7},

pages = {1048--1052},

doi = {10.1134/S0036024412070266}

}

MLA

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MLA Copy

Solomonov, A. V., et al. “The kinetics of oxidation of bilirubin and ascorbic acid in solution.” Russian Journal of Physical Chemistry A, vol. 86, no. 7, May. 2012, pp. 1048-1052. https://doi.org/10.1134/S0036024412070266.