Russian Journal of Physical Chemistry A, том 86, издание 11, номера страниц: 1639-1645

Kinetics of the dissociation of zinc(II) complexes with 3,3'-bis(dipyrrolylmethenes) in acetic acid-benzene binary solvent

Тип документаJournal Article
Дата публикации2012-09-29
ИздательPleiades Publishing
Название журналаRussian Journal of Physical Chemistry A
Квартиль по SCImagoQ4
Квартиль по Web of ScienceQ4
Импакт-фактор 20210.79
ISSN00360244, 1531863X
Physical and Theoretical Chemistry
Краткое описание
A comparative study of the dissociation of zinc(II) helicates with a series of 3,3′-bis(dipyrrolylmethenes) (H2L) of [Zn2L2] composition in acetic acid-benzene binary proton donor solvent in the temperature range from 298.15 to 318.15 K is performed by means of electronic spectroscopy. Quantitative kinetic characteristics are determined and a stoichiometric mechanism of reaction is suggested. It is established that the protolytic dissociation of [Zn2L2] helicates proceeds according to a third-order kinetic equation of reaction. The effect of alkyl substituents in the pyrrol rings and nature of central 3,3′-spacer on lability of helicates is analyzed.
Пристатейные ссылки: 18
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1. Antina L. A. и др. Kinetics of the dissociation of zinc(II) complexes with 3,3′-bis(dipyrrolylmethenes) in acetic acid-benzene binary solvent // Russian Journal of Physical Chemistry A. 2012. Т. 86. № 11. С. 1639–1645.
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TY - JOUR

DO - 10.1134/s0036024412110039

UR - http://dx.doi.org/10.1134/S0036024412110039

TI - Kinetics of the dissociation of zinc(II) complexes with 3,3′-bis(dipyrrolylmethenes) in acetic acid-benzene binary solvent

T2 - Russian Journal of Physical Chemistry A

AU - Antina, L. A.

AU - Guseva, G. B.

AU - V’yugin, A. I.

AU - Antina, E. V.

PY - 2012

DA - 2012/09/29

PB - Pleiades Publishing Ltd

SP - 1639-1645

IS - 11

VL - 86

SN - 0036-0244

SN - 1531-863X

ER -

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@article{Antina_2012,

doi = {10.1134/s0036024412110039},

url = {https://doi.org/10.1134%2Fs0036024412110039},

year = 2012,

month = {sep},

publisher = {Pleiades Publishing Ltd},

volume = {86},

number = {11},

pages = {1639--1645},

author = {L. A. Antina and G. B. Guseva and A. I. V'yugin and E. V. Antina},

title = {Kinetics of the dissociation of zinc({II}) complexes with 3,3$\prime$-bis(dipyrrolylmethenes) in acetic acid-benzene binary solvent},

journal = {Russian Journal of Physical Chemistry A}

}

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Antina, L. A., et al. “Kinetics of the Dissociation of Zinc(II) Complexes with 3,3′-Bis(Dipyrrolylmethenes) in Acetic Acid-Benzene Binary Solvent.” Russian Journal of Physical Chemistry A, vol. 86, no. 11, Sept. 2012, pp. 1639–45. Crossref, https://doi.org/10.1134/s0036024412110039.