Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia
K N Iost
1
,
N S Smirnova
2
,
V. A. Borisov
1, 3
,
V L Temerev
1
,
Yu V Surovikin
1
,
V.V. Kriventsov
4
,
E. V. Khramov
5
,
Ya. V. Zubavichus
4
,
M V Trenikhin
1, 3
,
E. Yu. Gerasimov
4
,
D.A Shlyapin
1
,
P.G Tsyrulnikov
1
2
4
Publication type: Journal Article
Publication date: 2020-10-30
scimago Q4
wos Q4
SJR: 0.204
CiteScore: 1.2
Impact factor: 0.8
ISSN: 00360244, 1531863X
Physical and Theoretical Chemistry
Abstract
The interaction between the components of a Ru–Rb/Sibunit catalyst for the decomposition of ammonia is studied via XAFS spectroscopy, X-ray diffraction with synchrotron radiation, and high-resolution transmission electron microscopy. The porous structure of the samples is examined at the stages of preparation. A set of measures reveals the presence of ruthenium in the catalyst (mainly in the metallic state) and the absence of joint phases of ruthenium and rubidium. It is found that rubidium is in an oxidized state in the catalyst in the form of compounds in direct contact with particles of active component and comparable in size to the latter, and as small clusters found mainly in the structure of carbon support.
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Iost K. N. et al. Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia // Russian Journal of Physical Chemistry A. 2020. Vol. 94. No. 11. pp. 2201-2208.
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Iost K. N., Smirnova N. S., Borisov V. A., Temerev V. L., Surovikin Yu. V., Kriventsov V., Khramov E., Zubavichus Y. V., Trenikhin M. V., Gerasimov E. Y., Shlyapin D., Tsyrulnikov P. Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia // Russian Journal of Physical Chemistry A. 2020. Vol. 94. No. 11. pp. 2201-2208.
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TY - JOUR
DO - 10.1134/S0036024420110114
UR - https://doi.org/10.1134/S0036024420110114
TI - Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia
T2 - Russian Journal of Physical Chemistry A
AU - Iost, K N
AU - Smirnova, N S
AU - Borisov, V. A.
AU - Temerev, V L
AU - Surovikin, Yu V
AU - Kriventsov, V.V.
AU - Khramov, E. V.
AU - Zubavichus, Ya. V.
AU - Trenikhin, M V
AU - Gerasimov, E. Yu.
AU - Shlyapin, D.A
AU - Tsyrulnikov, P.G
PY - 2020
DA - 2020/10/30
PB - Pleiades Publishing
SP - 2201-2208
IS - 11
VL - 94
SN - 0036-0244
SN - 1531-863X
ER -
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BibTex (up to 50 authors)
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@article{2020_Iost,
author = {K N Iost and N S Smirnova and V. A. Borisov and V L Temerev and Yu V Surovikin and V.V. Kriventsov and E. V. Khramov and Ya. V. Zubavichus and M V Trenikhin and E. Yu. Gerasimov and D.A Shlyapin and P.G Tsyrulnikov},
title = {Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia},
journal = {Russian Journal of Physical Chemistry A},
year = {2020},
volume = {94},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S0036024420110114},
number = {11},
pages = {2201--2208},
doi = {10.1134/S0036024420110114}
}
Cite this
MLA
Copy
Iost, K. N., et al. “Study of the Interaction between Components at Different Stages of Preparing Ru–Rb/Sibunit Catalysts for the Decomposition of Ammonia.” Russian Journal of Physical Chemistry A, vol. 94, no. 11, Oct. 2020, pp. 2201-2208. https://doi.org/10.1134/S0036024420110114.