Petroleum Chemistry

, volume 57 , issue 13 , pages 1219-1227

Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors

A A Lytkina ¹

N.V. Orekhova ¹

M.M. Ermilova ¹

I. S. Petriev ²

M. G. Baryshev ²

A. B. Yaroslavtsev ^{1, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia |

Kuban State University, Krasnodar, Russia |

Kurnakov institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2017-12-01

Pleiades Publishing

Petroleum Chemistry

scimago Q3

wos Q3

SJR: 0.272

CiteScore: 2.2

Impact factor: 1.1

ISSN: 09655441, 15556239

DOI: 10.1134/S0965544117130072

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General Chemistry

General Chemical Engineering

Geochemistry and Petrology

Energy Engineering and Power Technology

Fuel Technology

Abstract

Results of a study of the methanol steam reforming (MSR) catalytic process in conventional flow and membrane reactors in the presence of Ni0.2–Cu0.8 and Ru0.5–Rh0.5 catalysts supported on ZrO2 with a monoclinic, tetragonal, and cubic structure have been described. The cubic structure of zirconia has been stabilized with ceria. The samples have been characterized by X-ray diffraction analysis, transmission electron microscopy, and the BET method. It has been shown that the catalytic activity of the composites depends on the type of the metals and the structure of the support. It has been found that the Ru–Rh/Ce0.1Zr0.9O2–δ catalyst exhibits the highest activity, whereas Cu–Ni/Ce0.1Zr0.9O2–δ is the most selective. A comparative study of the MSR process in conventional and membrane reactors with Pd–Ru and modified Pd–Ag membranes has been conducted. The membrane process with a membrane based on a Pd–Ag alloy in the presence of the Ru–Rh/Ce0.1Zr0.9O2–δ catalyst provides a ~50% increase in the hydrogen yield.

Found

1 citation

Shostak Nikita

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PhD in Engineering, associate professor

30 publications, 63 citations

h-index: 3

Kuban State University

Kuban State Medical University

Kuban State Technological University

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Lytkina A. A. et al. Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors // Petroleum Chemistry. 2017. Vol. 57. No. 13. pp. 1219-1227.

GOST all authors (up to 50) Copy

Lytkina A. A., Orekhova N., Ermilova M., Petriev I. S., Baryshev M. G., Yaroslavtsev A. B. Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors // Petroleum Chemistry. 2017. Vol. 57. No. 13. pp. 1219-1227.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1134/S0965544117130072

UR - http://link.springer.com/10.1134/S0965544117130072

TI - Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors

T2 - Petroleum Chemistry

AU - Lytkina, A A

AU - Orekhova, N.V.

AU - Ermilova, M.M.

AU - Petriev, I. S.

AU - Baryshev, M. G.

AU - Yaroslavtsev, A. B.

PY - 2017

DA - 2017/12/01

PB - Pleiades Publishing

SP - 1219-1227

IS - 13

VL - 57

SN - 0965-5441

SN - 1555-6239

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2017_Lytkina,

author = {A A Lytkina and N.V. Orekhova and M.M. Ermilova and I. S. Petriev and M. G. Baryshev and A. B. Yaroslavtsev},

title = {Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors},

journal = {Petroleum Chemistry},

year = {2017},

volume = {57},

publisher = {Pleiades Publishing},

month = {dec},

url = {http://link.springer.com/10.1134/S0965544117130072},

number = {13},

pages = {1219--1227},

doi = {10.1134/S0965544117130072}

}

MLA

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MLA Copy

Lytkina, A. A., et al. “Methanol Steam Reforming over ZrO2-Supported Catalysts in Conventional and Membrane Reactors.” Petroleum Chemistry, vol. 57, no. 13, Dec. 2017, pp. 1219-1227. http://link.springer.com/10.1134/S0965544117130072.