volume 58 issue 13 pages 1144-1153

A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups

Publication typeJournal Article
Publication date2018-12-01
scimago Q3
wos Q3
SJR0.272
CiteScore2.2
Impact factor1.1
ISSN09655441, 15556239
General Chemistry
General Chemical Engineering
Geochemistry and Petrology
Energy Engineering and Power Technology
Fuel Technology
Abstract
Composite materials based on MF-4SK membranes (Plastpolimer, Russia), a membrane foil (Mega, Czech Republic), and phosphate-modified zirconia been synthesized; the transport properties of the composites in the proton and potassium forms have been studied. It has been found that the degree of doping of the heterogeneous membranes can be significantly higher than that of the homogeneous samples. It has been shown that the surface modification of zirconia with phosphate groups results in increase in the conductivity (from 0.0029 to 0.011 S/cm) and selectivity of transport processes improvement (from 0.068 to 0.009) in the membrane foil. Differences in the observed values of conductivity and mutual diffusion coefficient of the membranes in the hydrogen and potassium forms have been discussed taking into account the possible ion transport mechanisms.
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Yurova P. A., Stenina I. A., Yaroslavtsev A. B. A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups // Petroleum Chemistry. 2018. Vol. 58. No. 13. pp. 1144-1153.
GOST all authors (up to 50) Copy
Yurova P. A., Stenina I. A., Yaroslavtsev A. B. A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups // Petroleum Chemistry. 2018. Vol. 58. No. 13. pp. 1144-1153.
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TY - JOUR
DO - 10.1134/S0965544118130108
UR - http://link.springer.com/10.1134/S0965544118130108
TI - A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups
T2 - Petroleum Chemistry
AU - Yurova, P A
AU - Stenina, I A
AU - Yaroslavtsev, A. B.
PY - 2018
DA - 2018/12/01
PB - Pleiades Publishing
SP - 1144-1153
IS - 13
VL - 58
SN - 0965-5441
SN - 1555-6239
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Yurova,
author = {P A Yurova and I A Stenina and A. B. Yaroslavtsev},
title = {A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups},
journal = {Petroleum Chemistry},
year = {2018},
volume = {58},
publisher = {Pleiades Publishing},
month = {dec},
url = {http://link.springer.com/10.1134/S0965544118130108},
number = {13},
pages = {1144--1153},
doi = {10.1134/S0965544118130108}
}
MLA
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MLA Copy
Yurova, P. A., et al. “A Comparative Study of the Transport Properties of Homogeneous and Heterogeneous Cation-Exchange Membranes Doped with Zirconia Modified with Phosphoric Acid Groups.” Petroleum Chemistry, vol. 58, no. 13, Dec. 2018, pp. 1144-1153. http://link.springer.com/10.1134/S0965544118130108.