Pleiades Publishing
Polymer Science - Series A
,  volume 52 ,  issue 3 ,  pages 272-278

Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system

Publication type: Journal Article
Publication date: 2010-03-01
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
Intersolubility and interdiffusion in the oligo(3,3-bis(azidomethyl)oxetane)-oligo(3-methyl-3-azidomethyloxetane) binary system are studied. The components of the system differ in symmetric and non-symmetric positions of azide groups along the polymer chain, respectively. The chemical and conformational features ensure the ability of oligo(3,3-bis(azidomethyl)oxetane) to crystallize at temperatures of ∼50°C. The system of azidooxetane oligomers is characterized by a simple crystalline equilibrium crystal-melt. The generalized phase diagram of the binary system is constructed. The interdiffusion zones of oligomers are analyzed in detail in a wide temperature range, and a number of specific effects manifesting themselves during their intersolubility are observed. The concentration and temperature dependences of diffusion coefficients are examined, and the activation energies of diffusion are calculated.
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Kulagina G. S. et al. Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system // Polymer Science - Series A. 2010. Vol. 52. No. 3. pp. 272-278.
GOST all authors (up to 50) Copy
Kulagina G. S., Badamshina E. R., Mikhailov Y., Pisarev S. A., Khasbiullin R. R., Chalykh A. Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system // Polymer Science - Series A. 2010. Vol. 52. No. 3. pp. 272-278.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0965545X10030089
UR - https://doi.org/10.1134/S0965545X10030089
TI - Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system
T2 - Polymer Science - Series A
AU - Kulagina, G S
AU - Badamshina, E R
AU - Mikhailov, Yu.M.
AU - Pisarev, S A
AU - Khasbiullin, R R
AU - Chalykh, A.E.
PY - 2010
DA - 2010/03/01
PB - Pleiades Publishing
SP - 272-278
IS - 3
VL - 52
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Kulagina,
author = {G S Kulagina and E R Badamshina and Yu.M. Mikhailov and S A Pisarev and R R Khasbiullin and A.E. Chalykh},
title = {Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system},
journal = {Polymer Science - Series A},
year = {2010},
volume = {52},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S0965545X10030089},
number = {3},
pages = {272--278},
doi = {10.1134/S0965545X10030089}
}
MLA
Cite this
MLA Copy
Kulagina, G. S., et al. “Phase equilibrium and interdiffusion in the oligo(3,3-bis(azidomethyl) oxetane)-oligo(3-methyl-3-azidomethyloxetane) system.” Polymer Science - Series A, vol. 52, no. 3, Mar. 2010, pp. 272-278. https://doi.org/10.1134/S0965545X10030089.