Residual water in polyvinyl alcohol
R R Khasbiullin
1
,
Yu V Kostina
2
,
T F Petrova
1
,
G.N. Bondarenko
2
,
A.E. Chalykh
1
,
V F Chuvaev
1
,
V. K. Gerasimov
1
Publication type: Journal Article
Publication date: 2014-09-15
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
The state of sorbed water molecules in the matrix of polyvinyl alcohol is investigated via the methods of static sorption, DSC, TGA, IR Fourier spectroscopy, 1H NMR spectroscopy, and quantum-chemical simulation. It is shown that the sorption of water by polyvinyl alcohol characterized by an S-shaped isotherm is described by the double-sorption model. It is established that the low diffusion coefficients and extremely low rates of desorption processes observed in the range of low activities are determined by a shift of the equilibrium toward the formation of hydrogen-bonded complexes of water molecules with hydroxy groups of the polymer. A mechanism for the behavior of residual water in hydrophilic polymers is suggested. It implies that differences between polymers are determined only by the quantity of residual water immobilized in “traps” and the energy of hydrogen-bond formation.
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Total citations:
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Citations from 2025:
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(10%)
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GOST
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Khasbiullin R. R. et al. Residual water in polyvinyl alcohol // Polymer Science - Series A. 2014. Vol. 56. No. 5. pp. 569-578.
GOST all authors (up to 50)
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Khasbiullin R. R., Kostina Yu. V., Petrova T. F., Bondarenko G., Chalykh A., Chuvaev V. F., Gerasimov V. K. Residual water in polyvinyl alcohol // Polymer Science - Series A. 2014. Vol. 56. No. 5. pp. 569-578.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0965545X14050095
UR - https://doi.org/10.1134/S0965545X14050095
TI - Residual water in polyvinyl alcohol
T2 - Polymer Science - Series A
AU - Khasbiullin, R R
AU - Kostina, Yu V
AU - Petrova, T F
AU - Bondarenko, G.N.
AU - Chalykh, A.E.
AU - Chuvaev, V F
AU - Gerasimov, V. K.
PY - 2014
DA - 2014/09/15
PB - Pleiades Publishing
SP - 569-578
IS - 5
VL - 56
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Khasbiullin,
author = {R R Khasbiullin and Yu V Kostina and T F Petrova and G.N. Bondarenko and A.E. Chalykh and V F Chuvaev and V. K. Gerasimov},
title = {Residual water in polyvinyl alcohol},
journal = {Polymer Science - Series A},
year = {2014},
volume = {56},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S0965545X14050095},
number = {5},
pages = {569--578},
doi = {10.1134/S0965545X14050095}
}
Cite this
MLA
Copy
Khasbiullin, R. R., et al. “Residual water in polyvinyl alcohol.” Polymer Science - Series A, vol. 56, no. 5, Sep. 2014, pp. 569-578. https://doi.org/10.1134/S0965545X14050095.
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