volume 58 issue 5 pages 825-836

Microscopic mechanisms of diffusion of higher alkanes

G. E. Norman 1
1
 
Joint Institute for Higher Temperatures, Russian Academy of Sciences, Moscow, Russia
Publication typeJournal Article
Publication date2016-09-27
scimago Q3
wos Q4
SJR0.244
CiteScore1.9
Impact factor1.1
ISSN0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
With the use of n-triacontane models as examples, abnormal characteristics of diffusion that manifest themselves during the application of the Einstein–Smoluchowski relationship and the asymptotic behavior of velocity autocorrelation function of the molecule-mass centers that is used to calculate the diffusion coefficient via the Green–Kubo formula are investigated. On the basis of the data of complementary approaches, the microscopic mechanisms of diffusion in higher alkanes are outlined. The applicability of the Stokes–Einstein relationship for the viscosity coefficient is demonstrated.
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GOST |
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GOST Copy
Kondratyuk N. D. et al. Microscopic mechanisms of diffusion of higher alkanes // Polymer Science - Series A. 2016. Vol. 58. No. 5. pp. 825-836.
GOST all authors (up to 50) Copy
Kondratyuk N. D., Norman G. E., Stegailov V. V. Microscopic mechanisms of diffusion of higher alkanes // Polymer Science - Series A. 2016. Vol. 58. No. 5. pp. 825-836.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S0965545X16050072
UR - http://link.springer.com/10.1134/S0965545X16050072
TI - Microscopic mechanisms of diffusion of higher alkanes
T2 - Polymer Science - Series A
AU - Kondratyuk, N D
AU - Norman, G. E.
AU - Stegailov, V V
PY - 2016
DA - 2016/09/27
PB - Pleiades Publishing
SP - 825-836
IS - 5
VL - 58
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Kondratyuk,
author = {N D Kondratyuk and G. E. Norman and V V Stegailov},
title = {Microscopic mechanisms of diffusion of higher alkanes},
journal = {Polymer Science - Series A},
year = {2016},
volume = {58},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S0965545X16050072},
number = {5},
pages = {825--836},
doi = {10.1134/S0965545X16050072}
}
MLA
Cite this
MLA Copy
Kondratyuk, N. D., et al. “Microscopic mechanisms of diffusion of higher alkanes.” Polymer Science - Series A, vol. 58, no. 5, Sep. 2016, pp. 825-836. http://link.springer.com/10.1134/S0965545X16050072.