Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis
A A Yushkin
1
,
M N Efimov
1
,
A. A. Vasilev
1
,
V. I. Ivanov
2
,
Yu G Bogdanova
3
,
V D Dolzhikova
3
,
G. P. Karpacheva
1
,
G.N. Bondarenko
1
,
A.V. Volkov
1
Publication type: Journal Article
Publication date: 2017-11-01
scimago Q3
wos Q4
SJR: 0.244
CiteScore: 1.9
Impact factor: 1.1
ISSN: 0965545X, 15556107, 17571820
Materials Chemistry
Polymers and Plastics
Abstract
The effect of processing of polyacrylonitrile membranes by IR radiation at a temperature of 100–150°С is studied. The influence of the processing temperature on the film structure is ascertained. In a film heated at 100°С, a small amount of the double C=N bonds is found. Its further heating to 120°С is accompanied by a change in the chain conformation and an increase in the content of C=N bonds. It is shown that, upon IR processing at 120°С, polyacrylonitrile ceases to dissolve in N-methylpyrrolidone, dimethylacetamide, dimethylformamide, and dimethyl sulfoxide. Heating at 150°С gives rise to the appearance of conjugated С=N–C=N bonds. The analysis of AFM micrographs demonstrates that the processing of the membranes by IR radiation makes their surface rougher, while the size of pores changes slightly. The permeability of the membranes in various media is measured.
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Citations from 2024:
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GOST
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Yushkin A. A. et al. Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis // Polymer Science - Series A. 2017. Vol. 59. No. 6. pp. 880-890.
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Yushkin A. A., Efimov M. N., Vasilev A. A., Ivanov V. I., Bogdanova Yu. G., Dolzhikova V. D., Karpacheva G. P., Bondarenko G., Volkov A. Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis // Polymer Science - Series A. 2017. Vol. 59. No. 6. pp. 880-890.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0965545X17060104
UR - https://doi.org/10.1134/S0965545X17060104
TI - Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis
T2 - Polymer Science - Series A
AU - Yushkin, A A
AU - Efimov, M N
AU - Vasilev, A. A.
AU - Ivanov, V. I.
AU - Bogdanova, Yu G
AU - Dolzhikova, V D
AU - Karpacheva, G. P.
AU - Bondarenko, G.N.
AU - Volkov, A.V.
PY - 2017
DA - 2017/11/01
PB - Pleiades Publishing
SP - 880-890
IS - 6
VL - 59
SN - 0965-545X
SN - 1555-6107
SN - 1757-1820
ER -
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BibTex (up to 50 authors)
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@article{2017_Yushkin,
author = {A A Yushkin and M N Efimov and A. A. Vasilev and V. I. Ivanov and Yu G Bogdanova and V D Dolzhikova and G. P. Karpacheva and G.N. Bondarenko and A.V. Volkov},
title = {Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis},
journal = {Polymer Science - Series A},
year = {2017},
volume = {59},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0965545X17060104},
number = {6},
pages = {880--890},
doi = {10.1134/S0965545X17060104}
}
Cite this
MLA
Copy
Yushkin, A. A., et al. “Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis.” Polymer Science - Series A, vol. 59, no. 6, Nov. 2017, pp. 880-890. https://doi.org/10.1134/S0965545X17060104.