Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands
Publication type: Journal Article
Publication date: 2011-11-01
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
Electrochemical transformations of antimony(V) complexes containing a tridentate redoxactive ligand, N,N-bis-(2-hydroxy-di-3,5-tert-butylphenyl)amine: R 3Sb(Cat-NH-Cat) (R = (1) Ph; (2) Et), (3) Et2Sb(Cat-N-Cat)) are studied. Electrochemical oxidation of complexes 1, 2 occurs irreversibly leading to formation of unstable radical cations. The next stage is the chemical process resulting in formation of neutral paramagnetic compounds. The Et2Sb(V)(Cat-N-Cat) complex is characterized by two reversible anodic redox processes corresponding to a change of in the ligand redox level. Stable paramagnetic derivatives are formed as a result of electrochemical oxidation of compounds 1, 3; this allows considering these compounds as potential radical scavengers. Interaction of complex 1 with electrogenerated superoxide radical anion led to formation of paramagnetic reaction products.
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Smolyaninov I. V., Poddelskii A. I., Berberova N. T. Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands // Russian Journal of Electrochemistry. 2011. Vol. 47. No. 11. pp. 1211-1219.
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Smolyaninov I. V., Poddelskii A. I., Berberova N. T. Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands // Russian Journal of Electrochemistry. 2011. Vol. 47. No. 11. pp. 1211-1219.
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RIS
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TY - JOUR
DO - 10.1134/S1023193511100211
UR - https://doi.org/10.1134/S1023193511100211
TI - Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands
T2 - Russian Journal of Electrochemistry
AU - Smolyaninov, I V
AU - Poddelskii, A I
AU - Berberova, N T
PY - 2011
DA - 2011/11/01
PB - Pleiades Publishing
SP - 1211-1219
IS - 11
VL - 47
SN - 1023-1935
SN - 1608-3342
ER -
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BibTex (up to 50 authors)
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@article{2011_Smolyaninov,
author = {I V Smolyaninov and A I Poddelskii and N T Berberova},
title = {Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands},
journal = {Russian Journal of Electrochemistry},
year = {2011},
volume = {47},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1023193511100211},
number = {11},
pages = {1211--1219},
doi = {10.1134/S1023193511100211}
}
Cite this
MLA
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Smolyaninov, I. V., et al. “Electrochemical transformations of antimony(V) complexes containing tridentate O,N,O-donor ligands.” Russian Journal of Electrochemistry, vol. 47, no. 11, Nov. 2011, pp. 1211-1219. https://doi.org/10.1134/S1023193511100211.
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