Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases
Publication type: Journal Article
Publication date: 2018-10-01
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
In energy-storage systems such as fuel cells and metal-air batteries, the main current-forming process is the reaction of oxygen electroreduction (OER). A simple method is proposed for synthesizing OER catalysts based on polymer complexes of transition metals (nickel, palladium) with Schiff bases prepared by electrochemical polymerization of starting monomers. The OER catalysts are prepared by thermolysis of polymers in inert atmosphere. Their properties are characterized by the methods of cyclic voltammetry with the use of a rotating disk electrode. The surface state (the catalyst film density, the size and composition of particles) is controlled by scanning electron microscopy with X-ray microanalysis. The electrode demonstrates the high catalytic activity in the oxygen electroreduction reaction in alkaline solutions (higher than 750 mA/mg of the initial polymer mass).
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Novozhilova M. V. et al. Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 10. pp. 769-774.
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Novozhilova M. V., Danilova Yu. S., Karushev M. P., Timonov A. M., Malev V. V., Levin O. V. Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 10. pp. 769-774.
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TY - JOUR
DO - 10.1134/S102319351810004X
UR - https://doi.org/10.1134/S102319351810004X
TI - Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases
T2 - Russian Journal of Electrochemistry
AU - Novozhilova, M V
AU - Danilova, Yu S
AU - Karushev, M P
AU - Timonov, A M
AU - Malev, V V
AU - Levin, O. V.
PY - 2018
DA - 2018/10/01
PB - Pleiades Publishing
SP - 769-774
IS - 10
VL - 54
SN - 1023-1935
SN - 1608-3342
ER -
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BibTex (up to 50 authors)
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@article{2018_Novozhilova,
author = {M V Novozhilova and Yu S Danilova and M P Karushev and A M Timonov and V V Malev and O. V. Levin},
title = {Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases},
journal = {Russian Journal of Electrochemistry},
year = {2018},
volume = {54},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S102319351810004X},
number = {10},
pages = {769--774},
doi = {10.1134/S102319351810004X}
}
Cite this
MLA
Copy
Novozhilova, M. V., et al. “Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases.” Russian Journal of Electrochemistry, vol. 54, no. 10, Oct. 2018, pp. 769-774. https://doi.org/10.1134/S102319351810004X.
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