Russian Journal of Electrochemistry, volume 54, issue 11, pages 937-948
Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts
Menshchikov V S
1
,
Belenov S V
1
,
Guterman V E
1
,
Novomlinskiy I N
1
,
Nevelskaya A K
1
,
Nikulin A. Yu.
1
Publication type: Journal Article
Publication date: 2018-11-01
Journal:
Russian Journal of Electrochemistry
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.2
ISSN: 10231935, 16083342
Electrochemistry
Abstract
We investigate the activity of bimetallic PtM/C (M = Ni, Co) catalysts with different microstructures and platinum catalysts supported on a nanostructured composite carrier (SnO2/C) in the electrooxidation reaction of methanol. For bimetallic catalysts, the effect of heat treatment on their structural and functional characteristics is also studied. Among bimetallic catalysts in the as-obtained state, the Pt@Ni/C catalyst prepared by the subsequent reduction of nickel and platinum from solutions of their compounds exhibited the highest activity in the methanol electrooxidation, significantly exceeding that for the commercial Pt/C product. Heat treatment at 350°C increased the activity of the PtCo/C catalyst containing nanoparticles of a solid solution but adversely affected the tolerance of all the studied bimetallic catalysts to the intermediate products of methanol oxidation. All the studied Pt/(SnO2/C) materials demonstrated a higher mass activity in the electrooxidation reaction of methanol compared to commercial Pt/C and bimetallic systems, while the catalyst with a weight fraction of platinum of 12% and a molar ratio of Pt: SnO2 of 1: 1.1 showed the highest mass activity.
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Citations by publishers
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Multidisciplinary Digital Publishing Institute (MDPI)
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1 publication, 14.29%
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Wiley
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1 publication, 14.29%
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1 publication, 14.29%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Menshchikov V. S. et al. Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 11. pp. 937-948.
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Menshchikov V. S., Belenov S. V., Guterman V. E., Novomlinskiy I. N., Nevelskaya A. K., Nikulin A. Y. Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 11. pp. 937-948.
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TY - JOUR
DO - 10.1134/S1023193518130293
UR - https://doi.org/10.1134%2FS1023193518130293
TI - Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts
T2 - Russian Journal of Electrochemistry
AU - Menshchikov, V S
AU - Belenov, S V
AU - Nevelskaya, A K
AU - Nikulin, A. Yu.
AU - Guterman, V E
AU - Novomlinskiy, I N
PY - 2018
DA - 2018/11/01 00:00:00
PB - Pleiades Publishing
SP - 937-948
IS - 11
VL - 54
SN - 1023-1935
SN - 1608-3342
ER -
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@article{2018_Menshchikov,
author = {V S Menshchikov and S V Belenov and A K Nevelskaya and A. Yu. Nikulin and V E Guterman and I N Novomlinskiy},
title = {Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts},
journal = {Russian Journal of Electrochemistry},
year = {2018},
volume = {54},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134%2FS1023193518130293},
number = {11},
pages = {937--948},
doi = {10.1134/S1023193518130293}
}
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MLA
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Menshchikov, V. S., et al. “Methanol Electrooxidation on PtM/C (M = Ni, Co) and Pt/(SnO2/C) Catalysts.” Russian Journal of Electrochemistry, vol. 54, no. 11, Nov. 2018, pp. 937-948. https://doi.org/10.1134%2FS1023193518130293.