Russian Journal of Electrochemistry, volume 54, issue 11, pages 979-989

Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions

Publication typeJournal Article
Publication date2018-11-01
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor1.2
ISSN10231935, 16083342
Electrochemistry
Abstract
Stability is one of the most important characteristics of electrocatalysts used in low-temperature fuel cells with a proton exchange membrane. The corrosion-morphological stability of supported electrocatalysts containing platinum and platinum-copper nanoparticles with ~20 wt % Pt was evaluated under the conditions of voltammetry stress testing corresponding to different degradation mechanisms. The effect of the difference in the architecture of Pt–Cu nanoparticles on the stability of catalysts and changes in their composition as a result of stress tests were studied. At close values of the electrochemically active surface area (ECAS), the carbon-supported bimetallic catalysts demonstrated significantly higher stability compared to the commercial Pt/C catalysts. The Pt(Cu)/C catalyst obtained by sequential deposition of copper and platinum showed the highest resistance to the degradation and selective dissolution of copper during the testing.

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Moguchikh E. A. et al. Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 11. pp. 979-989.
GOST all authors (up to 50) Copy
Moguchikh E. A., Alekseenko A. A., Guterman V. E., Novikovsky N. M., Tabachkova, N. Y., Menshchikov V. S. Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions // Russian Journal of Electrochemistry. 2018. Vol. 54. No. 11. pp. 979-989.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S102319351813030X
UR - https://doi.org/10.1134%2FS102319351813030X
TI - Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions
T2 - Russian Journal of Electrochemistry
AU - Moguchikh, E A
AU - Alekseenko, A A
AU - Novikovsky, N M
AU - Tabachkova,, N. Yu.
AU - Menshchikov, V S
AU - Guterman, V E
PY - 2018
DA - 2018/11/01 00:00:00
PB - Pleiades Publishing
SP - 979-989
IS - 11
VL - 54
SN - 1023-1935
SN - 1608-3342
ER -
BibTex |
Cite this
BibTex Copy
@article{2018_Moguchikh,
author = {E A Moguchikh and A A Alekseenko and N M Novikovsky and N. Yu. Tabachkova, and V S Menshchikov and V E Guterman},
title = {Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions},
journal = {Russian Journal of Electrochemistry},
year = {2018},
volume = {54},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134%2FS102319351813030X},
number = {11},
pages = {979--989},
doi = {10.1134/S102319351813030X}
}
MLA
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MLA Copy
Moguchikh, E. A., et al. “Effect of the Composition and Structure of Pt(Cu)/C Electrocatalysts on Their Stability under Different Stress Test Conditions.” Russian Journal of Electrochemistry, vol. 54, no. 11, Nov. 2018, pp. 979-989. https://doi.org/10.1134%2FS102319351813030X.
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