Russian Journal of Electrochemistry, volume 55, issue 5, pages 438-448
Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts
Publication type: Journal Article
Publication date: 2019-05-01
Journal:
Russian Journal of Electrochemistry
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 1.2
ISSN: 10231935, 16083342
Electrochemistry
Abstract
Materials containing from 3.1 to 7.7 wt % of cobalt were obtained by electrodeposition of cobalt on Vulcan XC72 carbon powder in suspension. The composition and average diameter of CoO crystallites formed as result of cobalt oxidation in the process of filtering and drying materials, depending on the electrolysis conditions and electrolyte composition, were studied using thermogravimetry and XRD. It is shown that the maximum amount of cobalt can be deposited from electrolytes containing, along with cobalt sulfate, additives of copper and nickel sulfates. Calculations by the Scherrer equation showed that an increase in the CoO content leads to a decrease in the diameter of crystallites, the size of which is in the nano-range. The analysis of X-ray and electrochemical studies indicates the formation, in the course of the borohydride’s synthesis, of combined catalysts containing nanoparticles of the Pt3Co solid solution. The best PtCo/C material demonstrated significant improvement in ORR activity and superior stability compared to commercial Pt/C catalyst of the same platinum loading.
Citations by journals
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Russian Journal of General Chemistry
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Russian Journal of General Chemistry
1 publication, 100%
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1
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Citations by publishers
1
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Pleiades Publishing
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Pleiades Publishing
1 publication, 100%
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1
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Skibina L. M. et al. Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 5. pp. 438-448.
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Skibina L. M., Mauer D. K., Volochaev V. A., Guterman V. E. Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 5. pp. 438-448.
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TY - JOUR
DO - 10.1134/S1023193519050136
UR - https://doi.org/10.1134%2FS1023193519050136
TI - Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts
T2 - Russian Journal of Electrochemistry
AU - Skibina, L M
AU - Mauer, D K
AU - Volochaev, V A
AU - Guterman, V E
PY - 2019
DA - 2019/05/01 00:00:00
PB - Pleiades Publishing
SP - 438-448
IS - 5
VL - 55
SN - 1023-1935
SN - 1608-3342
ER -
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@article{2019_Skibina
author = {L M Skibina and D K Mauer and V A Volochaev and V E Guterman},
title = {Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts},
journal = {Russian Journal of Electrochemistry},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134%2FS1023193519050136},
number = {5},
pages = {438--448},
doi = {10.1134/S1023193519050136}
}
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MLA
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Skibina, L. M., et al. “Nanostructured Cobalt-Containing Carbon Supports for New Platinum Catalysts.” Russian Journal of Electrochemistry, vol. 55, no. 5, May. 2019, pp. 438-448. https://doi.org/10.1134%2FS1023193519050136.