Pleiades Publishing
Russian Journal of Electrochemistry
,  volume 55 ,  issue 10 ,  pages 1034-1038

Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x

Publication type: Journal Article
Publication date: 2019-10-01
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.236
CiteScore: 1.9
Impact factor: 0.8
ISSN: 10231935, 16083342
Electrochemistry
Abstract
Arsenate phosphates NaZr2(AsO4)x(PO4)3 –x are synthesized by the sol–gel method with subsequent annealing at 1123 K. Thus obtained specimens are investigated using X-ray diffraction analysis, IR and impedance spectroscopy. In the NaZr2(AsO4)x(PO4)3 –x system, continuous solid solution (0 ≤ x ≤ 3) with NaZr2(PO4)3 (NASICON) structure forms. According to the impedance spectroscopy data, an increase of the content of arsenic in the NaZr2(AsO4)x(PO4)3 –x system leads to an increase of the sodium-ionic conductivity; for NaZr2(AsO4)3, it reaches 8 × 10–5 S/cm at 773 K. At the same time, the activation energy of conductivity of this material (50 ± 1 kJ/mol) appears to be twice lower than the activation energy of conductivity of NaZr2(PO4)3 (100 ± 1 kJ/mol).
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Pet’kov V. et al. Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 10. pp. 1034-1038.
GOST all authors (up to 50) Copy
Pet’kov V., Shipilov A. S., Borovikova E., Stenina I. A., Yaroslavtsev A. B. Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 10. pp. 1034-1038.
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RIS Copy
TY - JOUR
DO - 10.1134/S1023193519100070
UR - http://link.springer.com/10.1134/S1023193519100070
TI - Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x
T2 - Russian Journal of Electrochemistry
AU - Pet’kov, V.I.
AU - Shipilov, A S
AU - Borovikova, E.Yu.
AU - Stenina, I A
AU - Yaroslavtsev, A. B.
PY - 2019
DA - 2019/10/01
PB - Pleiades Publishing
SP - 1034-1038
IS - 10
VL - 55
SN - 1023-1935
SN - 1608-3342
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2019_Pet’kov,
author = {V.I. Pet’kov and A S Shipilov and E.Yu. Borovikova and I A Stenina and A. B. Yaroslavtsev},
title = {Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x},
journal = {Russian Journal of Electrochemistry},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S1023193519100070},
number = {10},
pages = {1034--1038},
doi = {10.1134/S1023193519100070}
}
MLA
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MLA Copy
Pet’kov, V.I., et al. “Synthesis and Ionic Conductivity of NaZr2(AsO4)x(PO4)3 –x.” Russian Journal of Electrochemistry, vol. 55, no. 10, Oct. 2019, pp. 1034-1038. http://link.springer.com/10.1134/S1023193519100070.