Russian Journal of Electrochemistry, volume 55, issue 12, pages 1258-1268

De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction

Publication typeJournal Article
Publication date2019-12-01
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor1.2
ISSN10231935, 16083342
Electrochemistry
Abstract
Platinum-containing bimetallic nanoparticles manifest high functional characteristics as electrocatalysts. To use PtCu/C catalysts in low-temperature fuel cells, it is necessary to minimize selective copper dissolution, as copper cations can pollute the polymer membrane and decrease its proton conductivity. The work determines the composition, measures the electrochemically active surface area, and studies the electrochemical behavior of PtCu/C catalysts containing nanoparticles with a “core–shell” structure in the initial state (as-prepared) and after pretreatment in solutions of different acids. The comparative determination of catalyst activity in an electrochemical cell and their testing in a membrane-electrode assembly of fuel cells showed that pretreated PtCu/C materials with a much better stability as compared to Pt/C were also noninferior to the latter as regards their activity in the oxygen electroreduction reaction.

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GOST Copy
Kirakosyan S. A. et al. De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 12. pp. 1258-1268.
GOST all authors (up to 50) Copy
Kirakosyan S. A., Alekseenko A. A., Guterman V. E., Novomlinskii I. N., Menshchikov V. S., Gerasimova E. V., Nikulin A. Y. De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction // Russian Journal of Electrochemistry. 2019. Vol. 55. No. 12. pp. 1258-1268.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1134/S1023193519120085
UR - https://doi.org/10.1134%2FS1023193519120085
TI - De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction
T2 - Russian Journal of Electrochemistry
AU - Kirakosyan, S A
AU - Alekseenko, A A
AU - Novomlinskii, I N
AU - Menshchikov, V S
AU - Gerasimova, E V
AU - Nikulin, A. Yu.
AU - Guterman, V E
PY - 2019
DA - 2019/12/01 00:00:00
PB - Pleiades Publishing
SP - 1258-1268
IS - 12
VL - 55
SN - 1023-1935
SN - 1608-3342
ER -
BibTex |
Cite this
BibTex Copy
@article{2019_Kirakosyan,
author = {S A Kirakosyan and A A Alekseenko and I N Novomlinskii and V S Menshchikov and E V Gerasimova and A. Yu. Nikulin and V E Guterman},
title = {De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction},
journal = {Russian Journal of Electrochemistry},
year = {2019},
volume = {55},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134%2FS1023193519120085},
number = {12},
pages = {1258--1268},
doi = {10.1134/S1023193519120085}
}
MLA
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MLA Copy
Kirakosyan, S. A., et al. “De-Alloyed PtCu/C Catalysts of Oxygen Electroreduction.” Russian Journal of Electrochemistry, vol. 55, no. 12, Dec. 2019, pp. 1258-1268. https://doi.org/10.1134%2FS1023193519120085.
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