Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface
V V Butova
1
,
O A Burachevskaya
1
,
P V Medvedev
1
,
I E Gorban
1
,
A A Kuzharov
1
,
D B Trushina
2, 3
,
2
Publication type: Journal Article
Publication date: 2021-09-01
scimago Q4
wos Q4
SJR: 0.165
CiteScore: 0.8
Impact factor: 0.4
ISSN: 10274510, 18197094
Surfaces, Coatings and Films
Abstract
We report on a synthesis procedure for obtaining a UiO-66 metal-organic framework in the form of nanoparticles with a modified surface. A distinctive feature of the developed procedure is that modification occurs directly during synthesis. Biocompatible polyethylene glycol (PEG) is selected as the organic polymer covering the surface of the UiO-66 nanoparticles. The effect of the degree of PEG polymerization on the size, morphology, and surface charge of UiO-66 nanoparticles is studied. The presence of PEG molecules is confirmed by infrared (IR) spectroscopy. The materials obtained are single phase and characterized by a high degree of crystallinity. The particle size varies from 80 to 120 nm, depending on the type of PEG used. A high surface charge in an aqueous medium (ζ-potential over 20 mV) indicates the possibility of forming a stable suspension. Thus, the obtained materials are promising as nanocontainers for the delivery of biologically active substances.
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Butova V. V. et al. Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface // Journal of Surface Investigation. 2021. Vol. 15. No. 5. pp. 920-926.
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Butova V. V., Burachevskaya O. A., Medvedev P. V., Gorban I. E., Kuzharov A. A., Trushina D. B., Soldatov M. A. Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface // Journal of Surface Investigation. 2021. Vol. 15. No. 5. pp. 920-926.
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TY - JOUR
DO - 10.1134/S1027451021050037
UR - https://doi.org/10.1134/S1027451021050037
TI - Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface
T2 - Journal of Surface Investigation
AU - Butova, V V
AU - Burachevskaya, O A
AU - Medvedev, P V
AU - Gorban, I E
AU - Kuzharov, A A
AU - Trushina, D B
AU - Soldatov, M A
PY - 2021
DA - 2021/09/01
PB - Pleiades Publishing
SP - 920-926
IS - 5
VL - 15
SN - 1027-4510
SN - 1819-7094
ER -
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BibTex (up to 50 authors)
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@article{2021_Butova,
author = {V V Butova and O A Burachevskaya and P V Medvedev and I E Gorban and A A Kuzharov and D B Trushina and M A Soldatov},
title = {Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface},
journal = {Journal of Surface Investigation},
year = {2021},
volume = {15},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1027451021050037},
number = {5},
pages = {920--926},
doi = {10.1134/S1027451021050037}
}
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MLA
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Butova, V. V., et al. “Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface.” Journal of Surface Investigation, vol. 15, no. 5, Sep. 2021, pp. 920-926. https://doi.org/10.1134/S1027451021050037.