Colloid Journal, volume 83, issue 5, pages 614-626
Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide
Publication type: Journal Article
Publication date: 2021-09-01
Journal:
Colloid Journal
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 1.1
ISSN: 1061933X, 16083067
Physical and Theoretical Chemistry
Colloid and Surface Chemistry
Surfaces and Interfaces
Abstract
Metal-organic frameworks (MOFs) integrated with inorganic colloidal carriers compose a new class of functional hybrid materials possessing properties useful for a number of applications, in particular, selective sorption and (photo)catalysis. A new method has been developed for the synthesis of porous composites consisting of graphene oxide and MOF crystallites based on porphyrins. Graphene oxide serves simultaneously as a protective matrix for MOF and an emulsifier providing the assembly of immiscible components, which have different solubilities, in Pickering emulsions. Zinc acetate plays the role of a metal cluster, which immobilizes MOF crystallites on graphene oxide surface and participates in the MOF synthesis as a secondary structural block. This combination of the components makes it possible to avoid a chemical modification of graphene oxide during the assembly of the composite material. This strategy has been employed to obtain two series of model supramolecular composites based on zinc meso-tetra(4-pyridyl)porphyrinate and zinc meso-di(4-pyridyl)-di(4-carboxyphenyl)pophyrinate and study the relation between their structure, morphology, and properties. The developed colloid-chemical method makes it possible to simplify the synthesis of supramolecular composite materials and may be adapted to different combinations of inorganic matrices and MOFs.
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Citations by publishers
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Pleiades Publishing
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2 publications, 33.33%
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1 publication, 16.67%
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Multidisciplinary Digital Publishing Institute (MDPI)
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1 publication, 16.67%
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1 publication, 16.67%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Nugmanova A. G., Kalinina M. A. Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide // Colloid Journal. 2021. Vol. 83. No. 5. pp. 614-626.
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Nugmanova A. G., Kalinina M. A. Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide // Colloid Journal. 2021. Vol. 83. No. 5. pp. 614-626.
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TY - JOUR
DO - 10.1134/S1061933X21050094
UR - https://doi.org/10.1134%2FS1061933X21050094
TI - Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide
T2 - Colloid Journal
AU - Nugmanova, A G
AU - Kalinina, M A
PY - 2021
DA - 2021/09/01 00:00:00
PB - Pleiades Publishing
SP - 614-626
IS - 5
VL - 83
SN - 1061-933X
SN - 1608-3067
ER -
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@article{2021_Nugmanova,
author = {A G Nugmanova and M A Kalinina},
title = {Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide},
journal = {Colloid Journal},
year = {2021},
volume = {83},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134%2FS1061933X21050094},
number = {5},
pages = {614--626},
doi = {10.1134/S1061933X21050094}
}
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Nugmanova, A. G., and M A Kalinina. “Self-Assembly of Metal-Organic Frameworks in Pickering Emulsions Stabilized with Graphene Oxide.” Colloid Journal, vol. 83, no. 5, Sep. 2021, pp. 614-626. https://doi.org/10.1134%2FS1061933X21050094.
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