volume 73 issue 14 pages 1323-1326

Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry

Publication typeJournal Article
Publication date2018-12-01
scimago Q3
wos Q4
SJR0.252
CiteScore1.9
Impact factor1.1
ISSN10619348, 16083199
Analytical Chemistry
Abstract
A new method of the derivatization of alcohols for their analysis by matrix-assisted laser desorption/ionization (MALDI) and surface-assisted laser desorption/ionization (SALDI) is proposed. The approach is based on the silylation of the analytes with bromomethylchlorodimethylsilane in the presence of tertiary amines to yield fixed-charge containing derivatives. The proposed method was tested using aliphatic alcohols, terpenols, and sterols. MALDI and SALDI mass spectra of all derivatives contain intense ion peaks corresponding to their cationic parts.
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Zhilyaev D. I. et al. Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry // Journal of Analytical Chemistry. 2018. Vol. 73. No. 14. pp. 1323-1326.
GOST all authors (up to 50) Copy
Zhilyaev D. I., Voskresensky L. G., Polovkov N. Yu., Borisov R. S. Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry // Journal of Analytical Chemistry. 2018. Vol. 73. No. 14. pp. 1323-1326.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1061934818140149
UR - https://doi.org/10.1134/S1061934818140149
TI - Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry
T2 - Journal of Analytical Chemistry
AU - Zhilyaev, D I
AU - Voskresensky, L G
AU - Polovkov, N Yu
AU - Borisov, R S
PY - 2018
DA - 2018/12/01
PB - Pleiades Publishing
SP - 1323-1326
IS - 14
VL - 73
SN - 1061-9348
SN - 1608-3199
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2018_Zhilyaev,
author = {D I Zhilyaev and L G Voskresensky and N Yu Polovkov and R S Borisov},
title = {Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry},
journal = {Journal of Analytical Chemistry},
year = {2018},
volume = {73},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1061934818140149},
number = {14},
pages = {1323--1326},
doi = {10.1134/S1061934818140149}
}
MLA
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MLA Copy
Zhilyaev, D. I., et al. “Silylation with the Generation of a Fixed Charge for the Analysis of Alcohols by MALDI and SALDI Mass Spectrometry.” Journal of Analytical Chemistry, vol. 73, no. 14, Dec. 2018, pp. 1323-1326. https://doi.org/10.1134/S1061934818140149.