volume 52 issue 5 pages 819-825

Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex

G G Sadikov 1
A S Antsyshkina 1
T V Koksharova 2
I. S. Gritsenko 2
Publication typeJournal Article
Publication date2007-09-28
scimago Q4
wos Q4
SJR0.145
CiteScore0.8
Impact factor0.5
ISSN10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
AbstractThe [Co2L4(C4H9COO)4(H2O)] coordination compound of cobalt(II) valerate with nicotinamide (L) is synthesized and studied by IR spectroscopy. The crystal structure of the synthesized compound is determined. The crystals are triclinic, and the unit cell parameters are as follows: a = 10.2759(10) Å, b = 16.3858(10) Å, c = 16.4262(10) Å, α = 100.538(10)°, β = 101.199(10)°, γ = 90.813 (10)°, Z = 2, and space group P $$\bar 1$$ . The structural units of the crystal are dimeric molecular complexes in which pairs of cobalt atoms are linked by triple bridges formed by oxygen atoms of two bidentately coordinated valerate anions and a water molecule. The octahedral coordination of each cobalt atom is complemented by the pyridine nitrogen atoms of two nicotinamide ligands and the oxygen atom of the monodentate valerate group. The hydrocarbon chains of the valerate anions are disordered over two or three positions each.
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Sadikov G. G. et al. Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex // Crystallography Reports. 2007. Vol. 52. No. 5. pp. 819-825.
GOST all authors (up to 50) Copy
Sadikov G. G., Antsyshkina A. S., Koksharova T. V., Gritsenko I. S., Sergienko V. S. Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex // Crystallography Reports. 2007. Vol. 52. No. 5. pp. 819-825.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1063774507050112
UR - https://doi.org/10.1134/S1063774507050112
TI - Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex
T2 - Crystallography Reports
AU - Sadikov, G G
AU - Antsyshkina, A S
AU - Koksharova, T V
AU - Gritsenko, I. S.
AU - Sergienko, V S
PY - 2007
DA - 2007/09/28
PB - Pleiades Publishing
SP - 819-825
IS - 5
VL - 52
SN - 1063-7745
SN - 1562-689X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Sadikov,
author = {G G Sadikov and A S Antsyshkina and T V Koksharova and I. S. Gritsenko and V S Sergienko},
title = {Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex},
journal = {Crystallography Reports},
year = {2007},
volume = {52},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1063774507050112},
number = {5},
pages = {819--825},
doi = {10.1134/S1063774507050112}
}
MLA
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MLA Copy
Sadikov, G. G., et al. “Synthesis and crystal structure of the [Co2(Nicotinamide) 4(C4H9COO)4(H2O)] complex.” Crystallography Reports, vol. 52, no. 5, Sep. 2007, pp. 819-825. https://doi.org/10.1134/S1063774507050112.