Synthesis and crystal structure of the [WOCl3 {PhNHC(O)CHC(O-)Me} ] complex
Publication type: Journal Article
Publication date: 2009-09-01
scimago Q4
wos Q4
SJR: 0.145
CiteScore: 0.8
Impact factor: 0.5
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The [WOCl3{PhNHC(O)CHC(O−)Me}] complex has been synthesized, and its crystal structure has been determined. The coordination polyhedron of the tungsten atom is a distorted octahedron with a meridional arrangement of three chlorine atoms. Two oxygen atoms of the acetoacetanilide bidentate chelating ligand occupy trans positions to the O(3) oxo atom and the Cl(3) atom. The crystal structures and the IR spectra of the WOCl3{PhNHC(O)CHC(Ot-)Me} and [MoO2Cl2{(o-MePh)NHC(O)CH2C(O)Me}] complexes are compared.
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Ilyukhin A. B. et al. Synthesis and crystal structure of the [WOCl3{PhNHC(O)CHC(O-)Me} ] complex // Crystallography Reports. 2009. Vol. 54. No. 5. pp. 858-861.
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Ilyukhin A. B., Sergienko V. S., Abramenko V. L. Synthesis and crystal structure of the [WOCl3{PhNHC(O)CHC(O-)Me} ] complex // Crystallography Reports. 2009. Vol. 54. No. 5. pp. 858-861.
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TY - JOUR
DO - 10.1134/S1063774509050198
UR - http://link.springer.com/10.1134/S1063774509050198
TI - Synthesis and crystal structure of the [WOCl3{PhNHC(O)CHC(O-)Me} ] complex
T2 - Crystallography Reports
AU - Ilyukhin, A. B.
AU - Sergienko, V S
AU - Abramenko, V L
PY - 2009
DA - 2009/09/01
PB - Pleiades Publishing
SP - 858-861
IS - 5
VL - 54
SN - 1063-7745
SN - 1562-689X
ER -
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@article{2009_Ilyukhin,
author = {A. B. Ilyukhin and V S Sergienko and V L Abramenko},
title = {Synthesis and crystal structure of the [WOCl3{PhNHC(O)CHC(O-)Me} ] complex},
journal = {Crystallography Reports},
year = {2009},
volume = {54},
publisher = {Pleiades Publishing},
month = {sep},
url = {http://link.springer.com/10.1134/S1063774509050198},
number = {5},
pages = {858--861},
doi = {10.1134/S1063774509050198}
}
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Ilyukhin, A. B., et al. “Synthesis and crystal structure of the [WOCl3{PhNHC(O)CHC(O-)Me} ] complex.” Crystallography Reports, vol. 54, no. 5, Sep. 2009, pp. 858-861. http://link.springer.com/10.1134/S1063774509050198.