Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O
Publication type: Journal Article
Publication date: 2015-03-23
scimago Q4
wos Q4
SJR: 0.145
CiteScore: 0.8
Impact factor: 0.5
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The crystal structure of a new modification of the niahite mineral NH4MnPO4 · H2O, obtained in the form of single crystals under hydrothermal conditions in the Mn2O3-(NH4)3PO4-H2O system, is determined by X-ray diffraction (Xcalibur-S-CCD diffractometer, R = 0.0259): a = 17.582, b = 4.909, and c = 5.731 Å; space group D2h16 = Pnam, Z = 4, Dx = 2.497 g/cm3. It is shown that the new compound is a polymorphic modification of niahite; it has a layered structure, which differs from the structure of the mineral by the presence of the center of inversion and the doubled a unit cell parameter. It is proposed to consider the minerals and synthetic analogues of the niahite and triphylite groups as members of the common polysomatic series.
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Kiriukhina G. V. et al. Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O // Crystallography Reports. 2015. Vol. 60. No. 2. pp. 198-203.
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Kiriukhina G. V., Yakubovich O. V., Dimitrova O. V. Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O // Crystallography Reports. 2015. Vol. 60. No. 2. pp. 198-203.
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TY - JOUR
DO - 10.1134/S106377451502011X
UR - https://doi.org/10.1134/S106377451502011X
TI - Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O
T2 - Crystallography Reports
AU - Kiriukhina, G V
AU - Yakubovich, O. V.
AU - Dimitrova, O V
PY - 2015
DA - 2015/03/23
PB - Pleiades Publishing
SP - 198-203
IS - 2
VL - 60
SN - 1063-7745
SN - 1562-689X
ER -
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BibTex (up to 50 authors)
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@article{2015_Kiriukhina,
author = {G V Kiriukhina and O. V. Yakubovich and O V Dimitrova},
title = {Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O},
journal = {Crystallography Reports},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S106377451502011X},
number = {2},
pages = {198--203},
doi = {10.1134/S106377451502011X}
}
Cite this
MLA
Copy
Kiriukhina, G. V., et al. “Crystal structure of a new polymorphic modification of niahite, NH4MnPO4 · H2O.” Crystallography Reports, vol. 60, no. 2, Mar. 2015, pp. 198-203. https://doi.org/10.1134/S106377451502011X.