Pleiades Publishing
Crystallography Reports
,  том 60 ,  издание 2 ,  страницы 204-209

Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid]

Тип публикации: Journal Article
Дата публикации: 2015-03-23
Pleiades Publishing
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БС2
SJR: 0.145
CiteScore: 0.8
Impact factor: 0.5
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
The synthesis and X-ray diffraction study of three heterometallic compounds of general formula {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼20 (III); H4Oedph = 1-hydroxyethylidenediphosphonic acid] are performed. The basis element of structures I–III is a hexanuclear complex anion [Ge(μ-Oedph)(μ-O)0.5(μ-OH)0.5]69−, in which bridging hydroxo and oxo ligands are statistically disordered with equally probability. Hexameric units are connected by Ln1(H2O)4 fragments into a framework whose channels are completely populated by disordered lanthanide atoms and water molecules.
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
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Sergienko V. S. et al. Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid] // Crystallography Reports. 2015. Vol. 60. No. 2. pp. 204-209.
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Sergienko V. S., Martsinko E. É., Ilyukhin A. B., Seifullina I. I. Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid] // Crystallography Reports. 2015. Vol. 60. No. 2. pp. 204-209.
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TY - JOUR
DO - 10.1134/S1063774515020236
UR - http://link.springer.com/10.1134/S1063774515020236
TI - Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid]
T2 - Crystallography Reports
AU - Sergienko, V S
AU - Martsinko, E É
AU - Ilyukhin, A. B.
AU - Seifullina, I I
PY - 2015
DA - 2015/03/23
PB - Pleiades Publishing
SP - 204-209
IS - 2
VL - 60
SN - 1063-7745
SN - 1562-689X
ER -
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@article{2015_Sergienko,
author = {V S Sergienko and E É Martsinko and A. B. Ilyukhin and I I Seifullina},
title = {Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid]},
journal = {Crystallography Reports},
year = {2015},
volume = {60},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S1063774515020236},
number = {2},
pages = {204--209},
doi = {10.1134/S1063774515020236}
}
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Sergienko, V. S., et al. “Synthesis and crystal and molecular structure of three heterometallic polymeric compounds {Ln2[LnGe6(μ-Oedph)6(μ-O)3(μ-OH)3(H2O)4] · xH2O}n [Ln = Nd, x ∼ 26 (I); Er, x ∼ 24 (II); Tm, x ∼ 20 (III); H4 Oedph = 1-hydroxyethylidenediphosphonic acid].” Crystallography Reports, vol. 60, no. 2, Mar. 2015, pp. 204-209. http://link.springer.com/10.1134/S1063774515020236.