Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K
E.S. Smirnova
1
,
O.A Alekseeva
1
,
A P Dudka
1
,
I. A. Verin
1
,
V V Artemov
1
,
L. N. Bezmaternykh
2
,
I. A. Gudim
2
,
K.V. Frolov
1
,
I S Lyubutin
1
Publication type: Journal Article
Publication date: 2016-07-29
scimago Q4
wos Q4
SJR: 0.145
CiteScore: 0.8
Impact factor: 0.5
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The structure of GdFe3(BO3)4 single crystals has been studied by X-ray diffraction at 293 and 90 K. The crystals are grown from a flux in the Bi2Mo3O12–B2O3–Li2MoO4–Gd2O3–Fe2O3 system. The results of chemical analysis and structural study show that these crystals contain bismuth as an impurity. It is found that bismuth atoms are located at gadolinium sites in the structure. A decrease in the temperature is accompanied by a lowering of the symmetry from sp. gr. R32 (at 293 K) to sp. gr. P3121 (at 90 K). The presence of two types of iron chains with different geometries at 90 K promotes a change in the magnetic properties of these crystals with a decrease in the temperature.
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Smirnova E. et al. Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K // Crystallography Reports. 2016. Vol. 61. No. 4. pp. 558-565.
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Smirnova E., Alekseeva O., Dudka A. P., Verin I. A., Artemov V. V., Bezmaternykh L. N., Gudim I. A., Frolov K., Lyubutin I. S. Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K // Crystallography Reports. 2016. Vol. 61. No. 4. pp. 558-565.
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RIS
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TY - JOUR
DO - 10.1134/S1063774516040192
UR - https://doi.org/10.1134/S1063774516040192
TI - Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K
T2 - Crystallography Reports
AU - Smirnova, E.S.
AU - Alekseeva, O.A
AU - Dudka, A P
AU - Verin, I. A.
AU - Artemov, V V
AU - Bezmaternykh, L. N.
AU - Gudim, I. A.
AU - Frolov, K.V.
AU - Lyubutin, I S
PY - 2016
DA - 2016/07/29
PB - Pleiades Publishing
SP - 558-565
IS - 4
VL - 61
SN - 1063-7745
SN - 1562-689X
ER -
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BibTex (up to 50 authors)
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@article{2016_Smirnova,
author = {E.S. Smirnova and O.A Alekseeva and A P Dudka and I. A. Verin and V V Artemov and L. N. Bezmaternykh and I. A. Gudim and K.V. Frolov and I S Lyubutin},
title = {Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K},
journal = {Crystallography Reports},
year = {2016},
volume = {61},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S1063774516040192},
number = {4},
pages = {558--565},
doi = {10.1134/S1063774516040192}
}
Cite this
MLA
Copy
Smirnova, E.S., et al. “Structure of Gd0.95Bi0.05Fe3(BO3)4 single crystals at 293 and 90 K.” Crystallography Reports, vol. 61, no. 4, Jul. 2016, pp. 558-565. https://doi.org/10.1134/S1063774516040192.
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