Pleiades Publishing
Crystallography Reports
,  volume 66 ,  issue 3 ,  pages 429-432

Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride

R Alabada
, 
O V Avramenko
, 
S B Strashnova
, 
V S Sergienko
, 
Ya Absalan
, 
O V Kovalchukova
Publication type: Journal Article
Publication date: 2021-05-25
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.145
CiteScore: 0.8
Impact factor: 0.5
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Abstract The crystal and molecular structure of 2-hydrazinobenzoic acid was determined. In solution in the presence of copper(II) chloride, 2-hydrazinobenzoic acid is transformed into 2-chlorobenzoic acid (HL 1 ) and is coordinated to copper(II) cations to form the binuclear structure [Cu(H 2 O)] 2 (µ-L 1 ) 4 with bridging carboxylate groups of the ligand (L 1 ) – . Three complexes of HL 1 with Fe(II), Co(II), and Zn(II) were isolated in the crystalline state and studied by spectroscopic methods. It was found that the organic molecules are involved in the complexes in the monodeprotonated chelating form.
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Alabada R. et al. Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride // Crystallography Reports. 2021. Vol. 66. No. 3. pp. 429-432.
GOST all authors (up to 50) Copy
Alabada R., Avramenko O. V., Strashnova S. B., Sergienko V. S., Absalan Ya., Kovalchukova O. V. Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride // Crystallography Reports. 2021. Vol. 66. No. 3. pp. 429-432.
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TY - JOUR
DO - 10.1134/S1063774521030032
UR - https://doi.org/10.1134/S1063774521030032
TI - Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride
T2 - Crystallography Reports
AU - Alabada, R
AU - Avramenko, O V
AU - Strashnova, S B
AU - Sergienko, V S
AU - Absalan, Ya
AU - Kovalchukova, O V
PY - 2021
DA - 2021/05/25
PB - Pleiades Publishing
SP - 429-432
IS - 3
VL - 66
SN - 1063-7745
SN - 1562-689X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2021_Alabada,
author = {R Alabada and O V Avramenko and S B Strashnova and V S Sergienko and Ya Absalan and O V Kovalchukova},
title = {Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride},
journal = {Crystallography Reports},
year = {2021},
volume = {66},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S1063774521030032},
number = {3},
pages = {429--432},
doi = {10.1134/S1063774521030032}
}
MLA
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MLA Copy
Alabada, R., et al. “Unusual Substitution in Hydrazinobenzoic Acid upon Complexation. Crystal and Molecular Structure of Hydrazinobenzoic Acid Hydrochloride.” Crystallography Reports, vol. 66, no. 3, May. 2021, pp. 429-432. https://doi.org/10.1134/S1063774521030032.