Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal
Yu V Gerasimova
1
,
A S Oreshonkov
1
,
A. N. Vtyurin
1
,
A. A. Ivanenko
1
,
L. I. Isaenko
2
,
A. A. Ershov
1
,
E. I. Pogoreltsev
1
Publication type: Journal Article
Publication date: 2013-11-05
scimago Q4
wos Q3
SJR: 0.183
CiteScore: 1.4
Impact factor: 1.8
ISSN: 10637834, 10906460, 17267498
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
The infrared absorption spectra of the oxyfluoride Rb2KMoO3F3 have been measured in the frequency range corresponding to stretching vibrations of the Mo-O anion octahedron with the purpose of clarifying their role in the phase transition. A semi-empirical calculation of two possible configurations of quasioctahedral MoO3F3 groups has been performed. The results of the investigations have demonstrated that some octahedra in the crystal structure change the local symmetry from C 3v to C 2v due to the phase transition (T = 197 K).
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Gerasimova Yu. V. et al. Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal // Physics of the Solid State. 2013. Vol. 55. No. 11. pp. 2331-2334.
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Gerasimova Yu. V., Oreshonkov A. S., Vtyurin A. N., Ivanenko A. A., Isaenko L. I., Ershov A. A., Pogoreltsev E. I. Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal // Physics of the Solid State. 2013. Vol. 55. No. 11. pp. 2331-2334.
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RIS
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TY - JOUR
DO - 10.1134/S1063783413110097
UR - http://link.springer.com/10.1134/S1063783413110097
TI - Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal
T2 - Physics of the Solid State
AU - Gerasimova, Yu V
AU - Oreshonkov, A S
AU - Vtyurin, A. N.
AU - Ivanenko, A. A.
AU - Isaenko, L. I.
AU - Ershov, A. A.
AU - Pogoreltsev, E. I.
PY - 2013
DA - 2013/11/05
PB - Pleiades Publishing
SP - 2331-2334
IS - 11
VL - 55
SN - 1063-7834
SN - 1090-6460
SN - 1726-7498
ER -
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BibTex (up to 50 authors)
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@article{2013_Gerasimova,
author = {Yu V Gerasimova and A S Oreshonkov and A. N. Vtyurin and A. A. Ivanenko and L. I. Isaenko and A. A. Ershov and E. I. Pogoreltsev},
title = {Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal},
journal = {Physics of the Solid State},
year = {2013},
volume = {55},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S1063783413110097},
number = {11},
pages = {2331--2334},
doi = {10.1134/S1063783413110097}
}
Cite this
MLA
Copy
Gerasimova, Yu. V., et al. “Infrared absorption investigation of the role of octahedral groups upon the phase transition in the Rb2KMoO3F3 crystal.” Physics of the Solid State, vol. 55, no. 11, Nov. 2013, pp. 2331-2334. http://link.springer.com/10.1134/S1063783413110097.