Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4
M A Prosnikov
1
,
A. D. Molchanova
2
,
R M Dubrovin
1
,
K N Boldyrev
2
,
A.N. Smirnov
2
,
V.Yu. Davydov
1
,
A. M. Balbashov
3
,
M.N. Popova
2
,
Тип публикации: Journal Article
Дата публикации: 2016-12-16
scimago Q4
wos Q3
БС2
SJR: 0.183
CiteScore: 1.4
Impact factor: 1.8
ISSN: 10637834, 10906460, 17267498
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Краткое описание
The results are presented on phonon excitations and the electronic structure of Co2TiO4 inverse spinel in which magnetically ordered cobalt ions Co2+ (3d 7) are in equal amounts in tetrahedral and octahedral sublattices below T C = 56 K. Single crystals are studied using optical reflection and absorption in a wide spectral range, Raman scattering, and dielectric spectroscopy methods. The dynamics of infrared and Raman-active phonons are studied, and the features associated with disordering in tetrahedral sites are detected. The d–d electronic transitions recorded in the regions of 3800 and 6300 cm–1 confirm the coordination features of Co2+ ions. An increase in the permittivity in the temperature region below 130 K is detected.
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Prosnikov M. A. et al. Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4 // Physics of the Solid State. 2016. Vol. 58. No. 12. pp. 2516-2522.
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Prosnikov M. A., Molchanova A. D., Dubrovin R. M., Boldyrev K. N., Smirnov A., Davydov V., Balbashov A. M., Popova M., PISAREV R. V. Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4 // Physics of the Solid State. 2016. Vol. 58. No. 12. pp. 2516-2522.
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TY - JOUR
DO - 10.1134/S1063783416120258
UR - https://doi.org/10.1134/S1063783416120258
TI - Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4
T2 - Physics of the Solid State
AU - Prosnikov, M A
AU - Molchanova, A. D.
AU - Dubrovin, R M
AU - Boldyrev, K N
AU - Smirnov, A.N.
AU - Davydov, V.Yu.
AU - Balbashov, A. M.
AU - Popova, M.N.
AU - PISAREV, R. V.
PY - 2016
DA - 2016/12/16
PB - Pleiades Publishing
SP - 2516-2522
IS - 12
VL - 58
SN - 1063-7834
SN - 1090-6460
SN - 1726-7498
ER -
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@article{2016_Prosnikov,
author = {M A Prosnikov and A. D. Molchanova and R M Dubrovin and K N Boldyrev and A.N. Smirnov and V.Yu. Davydov and A. M. Balbashov and M.N. Popova and R. V. PISAREV},
title = {Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4},
journal = {Physics of the Solid State},
year = {2016},
volume = {58},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1063783416120258},
number = {12},
pages = {2516--2522},
doi = {10.1134/S1063783416120258}
}
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MLA
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Prosnikov, M. A., et al. “Lattice dynamics and electronic structure of cobalt-titanium spinel Co2TiO4.” Physics of the Solid State, vol. 58, no. 12, Dec. 2016, pp. 2516-2522. https://doi.org/10.1134/S1063783416120258.
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