Electrochemical properties and dissolution of UPd3 in nitric acid solutions
Publication type: Journal Article
Publication date: 2016-09-01
scimago Q3
wos Q4
SJR: 0.285
CiteScore: 1.6
Impact factor: 1.0
ISSN: 10663622, 16083288
Physical and Theoretical Chemistry
Abstract
Electrochemical properties of the intermetallic compound UPd3 in 0.5–8 M HNO3 solutions were studied by linear voltammetry. In 0.5–2 M HNO3 solutions, the UPd3 surface is in the passive state. At HNO3 concentrations exceeding 4 M, the alloy passivation was not observed. The previously unknown electrochemical characteristics of UPd3 in nitric acid solutions were obtained using the Tafel equation. The values of Е(i = 0) and vcorr increased from 39 mV and 38 μg cm–2 h–1 in 0.5 M HNO3 to 821 mV and 11 mg cm–2 h–1 in 8 M HNO3, respectively. Dissolution experiments have shown that UPd3 can dissolve in HNO3 solutions of concentration exceeding 4 M at room temperature. In 8 M HNO3, the dissolution rate can reach 17 mg cm–2 h–1 at 25°С, with the dissolution being virtually equimolar and accelerating with time.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
|
|
|
Radiochemistry
3 publications, 60%
|
|
|
Journal of Nuclear Materials
2 publications, 40%
|
|
|
1
2
3
|
Publishers
|
1
2
3
|
|
|
Pleiades Publishing
3 publications, 60%
|
|
|
Elsevier
2 publications, 40%
|
|
|
1
2
3
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
5
Total citations:
5
Citations from 2024:
1
(20%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Zavarzin S. V. et al. Electrochemical properties and dissolution of UPd3 in nitric acid solutions // Radiochemistry. 2016. Vol. 58. No. 5. pp. 466-472.
GOST all authors (up to 50)
Copy
Zavarzin S. V., Maslennikov A. G., Gedgovd K. N., Bulatov G. S., Vlasova I. E. Electrochemical properties and dissolution of UPd3 in nitric acid solutions // Radiochemistry. 2016. Vol. 58. No. 5. pp. 466-472.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S1066362216050040
UR - https://doi.org/10.1134/S1066362216050040
TI - Electrochemical properties and dissolution of UPd3 in nitric acid solutions
T2 - Radiochemistry
AU - Zavarzin, S V
AU - Maslennikov, A G
AU - Gedgovd, K N
AU - Bulatov, G S
AU - Vlasova, I E
PY - 2016
DA - 2016/09/01
PB - Pleiades Publishing
SP - 466-472
IS - 5
VL - 58
SN - 1066-3622
SN - 1608-3288
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Zavarzin,
author = {S V Zavarzin and A G Maslennikov and K N Gedgovd and G S Bulatov and I E Vlasova},
title = {Electrochemical properties and dissolution of UPd3 in nitric acid solutions},
journal = {Radiochemistry},
year = {2016},
volume = {58},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1066362216050040},
number = {5},
pages = {466--472},
doi = {10.1134/S1066362216050040}
}
Cite this
MLA
Copy
Zavarzin, S. V., et al. “Electrochemical properties and dissolution of UPd3 in nitric acid solutions.” Radiochemistry, vol. 58, no. 5, Sep. 2016, pp. 466-472. https://doi.org/10.1134/S1066362216050040.
Profiles