Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS
K I Maslakov
1
,
Yu.A. Teterin
1, 2
,
O I Stefanovskaya
3
,
S N Kalmykov
1, 2, 3
,
A.Yu. Teterin
2
,
K.E. Ivanov
2
,
S. V. Yudintsev
3, 4
,
B. F. Myasoedov
3
Тип публикации: Journal Article
Дата публикации: 2020-05-01
scimago Q3
wos Q4
БС3
SJR: 0.285
CiteScore: 1.6
Impact factor: 1.0
ISSN: 10663622, 16083288
Physical and Theoretical Chemistry
Краткое описание
Samples of titanate zirconate ceramics based on phases of the murataite-pyrochlore series are studied by XPS. The analysis of the surface was performed and the oxidation states of the elements were determined. A comparison of XPS results and data on the total composition of the samples was carried out. On the surface, compared to the bulk, the Ti and Th content is lower, but the Fe content is higher. Despite the introduction of uranium into the blend in the form of UO2 or as uranyl nitrate, the samples contain approximately equal amounts of U(IV) and U(V). Iron is 93% Fe(III) and 7% Fe(II) forms.
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Maslakov K. I. et al. Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS // Radiochemistry. 2020. Vol. 62. No. 5. pp. 599-607.
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Maslakov K. I., Teterin Y., Stefanovskaya O. I., Kalmykov S. N., Teterin A., Ivanov K., Yudintsev S. V., Myasoedov B. F. Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS // Radiochemistry. 2020. Vol. 62. No. 5. pp. 599-607.
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TY - JOUR
DO - 10.1134/S1066362220050069
UR - https://doi.org/10.1134/S1066362220050069
TI - Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS
T2 - Radiochemistry
AU - Maslakov, K I
AU - Teterin, Yu.A.
AU - Stefanovskaya, O I
AU - Kalmykov, S N
AU - Teterin, A.Yu.
AU - Ivanov, K.E.
AU - Yudintsev, S. V.
AU - Myasoedov, B. F.
PY - 2020
DA - 2020/05/01
PB - Pleiades Publishing
SP - 599-607
IS - 5
VL - 62
SN - 1066-3622
SN - 1608-3288
ER -
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@article{2020_Maslakov,
author = {K I Maslakov and Yu.A. Teterin and O I Stefanovskaya and S N Kalmykov and A.Yu. Teterin and K.E. Ivanov and S. V. Yudintsev and B. F. Myasoedov},
title = {Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS},
journal = {Radiochemistry},
year = {2020},
volume = {62},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S1066362220050069},
number = {5},
pages = {599--607},
doi = {10.1134/S1066362220050069}
}
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Maslakov, K. I., et al. “Study of Titanate Zirconate Ceramics Based on the Phases of the Murataite-Pyrochloric Series Containing Th and U by XPS.” Radiochemistry, vol. 62, no. 5, May. 2020, pp. 599-607. https://doi.org/10.1134/S1066362220050069.