Radiochemistry, volume 63, issue 4, pages 401-412

The Valence XPS Structure and the Nature of Chemical Bond in CmO2

Publication typeJournal Article
Publication date2021-08-01
Journal: Radiochemistry
Quartile SCImago
Q3
Quartile WOS
Impact factor0.6
ISSN10663622, 16083288
Physical and Theoretical Chemistry
Abstract
In the approximation of the relativistic discrete variation method, the valence X-ray photoelectron spectrum of CmO2 was calculated, and satisfactory agreement with the structure of the experimental spectrum was found. It was shown that the structure of the spectrum is due to the electrons of the outer (from 0 to ~15 eV) and inner (from ~15 to ~35 eV) valence molecular orbitals, which leads to an increase in the covalency of the chemical bond in CmO2. The effective charge of curium in CmO2 was determined, and the contribution of various electrons to the chemical bond was evaluated. A semiempirical scheme of molecular orbitals for CmO2 was constructed.

Citations by journals

1
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry, 1, 50%
Russian Journal of Inorganic Chemistry
1 publication, 50%
Journal of Structural Chemistry
Journal of Structural Chemistry, 1, 50%
Journal of Structural Chemistry
1 publication, 50%
1

Citations by publishers

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Pleiades Publishing
Pleiades Publishing, 2, 100%
Pleiades Publishing
2 publications, 100%
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2
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Putkov A. E. et al. The Valence XPS Structure and the Nature of Chemical Bond in CmO2 // Radiochemistry. 2021. Vol. 63. No. 4. pp. 401-412.
GOST all authors (up to 50) Copy
Putkov A. E., Teterin Y., Ryzhkov M., Maslakov K. I., Teterin A., Ivanov K., Kalmykov S. N., Petrov V. G. The Valence XPS Structure and the Nature of Chemical Bond in CmO2 // Radiochemistry. 2021. Vol. 63. No. 4. pp. 401-412.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1066362221040020
UR - https://doi.org/10.1134%2FS1066362221040020
TI - The Valence XPS Structure and the Nature of Chemical Bond in CmO2
T2 - Radiochemistry
AU - Putkov, A E
AU - Teterin, Yu.A.
AU - Ryzhkov, M.V.
AU - Ivanov, K.E.
AU - Maslakov, K I
AU - Teterin, A.Yu.
AU - Kalmykov, S N
AU - Petrov, V. G.
PY - 2021
DA - 2021/08/01 00:00:00
PB - Pleiades Publishing
SP - 401-412
IS - 4
VL - 63
SN - 1066-3622
SN - 1608-3288
ER -
BibTex |
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BibTex Copy
@article{2021_Putkov
author = {A E Putkov and Yu.A. Teterin and M.V. Ryzhkov and K.E. Ivanov and K I Maslakov and A.Yu. Teterin and S N Kalmykov and V. G. Petrov},
title = {The Valence XPS Structure and the Nature of Chemical Bond in CmO2},
journal = {Radiochemistry},
year = {2021},
volume = {63},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS1066362221040020},
number = {4},
pages = {401--412},
doi = {10.1134/S1066362221040020}
}
MLA
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MLA Copy
Putkov, A. E., et al. “The Valence XPS Structure and the Nature of Chemical Bond in CmO2.” Radiochemistry, vol. 63, no. 4, Aug. 2021, pp. 401-412. https://doi.org/10.1134%2FS1066362221040020.
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