,
volume 32
,
issue 7
,
pages 518-523
Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes
G B Guseva
1
,
Publication type: Journal Article
Publication date: 2006-07-18
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Reactivity of 3,3′,5,5′-tetramethyl-4,4′dibutyldipyrrolylmethene (HL) in reactions Co(II) and Cu(II) acetates, acetylacetonates, and valinates in DMF (298.15 K) was estimated by spectrophotometric and calorimetric titration methods. The product of the exchange reaction between HL and Co acetate or acetylacetonate was found to be CoL2 complex. With an excess of Cu(II) acetate or acetylacetonate, the reaction resulted in mixed-ligand complexes CuL(AcO) and CuL(Acac), while with an excess of HL, the CuL2 complex was formed. Irrespective of the reagent concentration ratios, the exchange reactions with Cu(II) and Co(II) valinates gave ML(Val) complexes. Thermodynamic parameters of HL reactions with Cu(II) and Co(II) acetates, acetylacetonates, and valinates were determined.
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Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
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Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S1070328406070098
UR - https://doi.org/10.1134/S1070328406070098
TI - Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Guseva, G B
AU - Antina, E V
PY - 2006
DA - 2006/07/18
PB - Pleiades Publishing
SP - 518-523
IS - 7
VL - 32
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2006_Guseva,
author = {G B Guseva and E V Antina},
title = {Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2006},
volume = {32},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S1070328406070098},
number = {7},
pages = {518--523},
doi = {10.1134/S1070328406070098}
}
Cite this
MLA
Copy
Guseva, G. B., and E V Antina. “Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 32, no. 7, Jul. 2006, pp. 518-523. https://doi.org/10.1134/S1070328406070098.
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