Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 32, issue 7, pages 518-523
Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes
Guseva G B
1
,
Publication type: Journal Article
Publication date: 2006-07-18
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Reactivity of 3,3′,5,5′-tetramethyl-4,4′dibutyldipyrrolylmethene (HL) in reactions Co(II) and Cu(II) acetates, acetylacetonates, and valinates in DMF (298.15 K) was estimated by spectrophotometric and calorimetric titration methods. The product of the exchange reaction between HL and Co acetate or acetylacetonate was found to be CoL2 complex. With an excess of Cu(II) acetate or acetylacetonate, the reaction resulted in mixed-ligand complexes CuL(AcO) and CuL(Acac), while with an excess of HL, the CuL2 complex was formed. Irrespective of the reagent concentration ratios, the exchange reactions with Cu(II) and Co(II) valinates gave ML(Val) complexes. Thermodynamic parameters of HL reactions with Cu(II) and Co(II) acetates, acetylacetonates, and valinates were determined.
Citations by journals
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2
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Russian Journal of General Chemistry
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Russian Journal of General Chemistry
2 publications, 40%
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
1 publication, 20%
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Russian Journal of Inorganic Chemistry
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Russian Journal of Inorganic Chemistry
1 publication, 20%
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1
2
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Citations by publishers
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4
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Pleiades Publishing
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Pleiades Publishing
4 publications, 80%
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Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
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Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
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TY - JOUR
DO - 10.1134/S1070328406070098
UR - https://doi.org/10.1134%2FS1070328406070098
TI - Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Guseva, G B
AU - Antina, E V
PY - 2006
DA - 2006/07/18 00:00:00
PB - Pleiades Publishing
SP - 518-523
IS - 7
VL - 32
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2006_Guseva,
author = {G B Guseva and E V Antina},
title = {Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2006},
volume = {32},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS1070328406070098},
number = {7},
pages = {518--523},
doi = {10.1134/S1070328406070098}
}
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MLA
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Guseva, G. B., and E V Antina. “Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 32, no. 7, Jul. 2006, pp. 518-523. https://doi.org/10.1134%2FS1070328406070098.
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