Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 32, issue 7, pages 518-523

Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes

Publication typeJournal Article
Publication date2006-07-18
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.9
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Reactivity of 3,3′,5,5′-tetramethyl-4,4′dibutyldipyrrolylmethene (HL) in reactions Co(II) and Cu(II) acetates, acetylacetonates, and valinates in DMF (298.15 K) was estimated by spectrophotometric and calorimetric titration methods. The product of the exchange reaction between HL and Co acetate or acetylacetonate was found to be CoL2 complex. With an excess of Cu(II) acetate or acetylacetonate, the reaction resulted in mixed-ligand complexes CuL(AcO) and CuL(Acac), while with an excess of HL, the CuL2 complex was formed. Irrespective of the reagent concentration ratios, the exchange reactions with Cu(II) and Co(II) valinates gave ML(Val) complexes. Thermodynamic parameters of HL reactions with Cu(II) and Co(II) acetates, acetylacetonates, and valinates were determined.

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Citations by publishers

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Pleiades Publishing
Pleiades Publishing, 4, 80%
Pleiades Publishing
4 publications, 80%
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Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
GOST all authors (up to 50) Copy
Guseva G. B., Antina E. V. Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2006. Vol. 32. No. 7. pp. 518-523.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S1070328406070098
UR - https://doi.org/10.1134%2FS1070328406070098
TI - Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Guseva, G B
AU - Antina, E V
PY - 2006
DA - 2006/07/18 00:00:00
PB - Pleiades Publishing
SP - 518-523
IS - 7
VL - 32
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
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BibTex Copy
@article{2006_Guseva,
author = {G B Guseva and E V Antina},
title = {Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2006},
volume = {32},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2FS1070328406070098},
number = {7},
pages = {518--523},
doi = {10.1134/S1070328406070098}
}
MLA
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MLA Copy
Guseva, G. B., and E V Antina. “Reactivity of α,α-dipyrrolylmethene in reactions with some Co(II) and Cu(II) complexes.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 32, no. 7, Jul. 2006, pp. 518-523. https://doi.org/10.1134%2FS1070328406070098.
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