,
volume 33
,
issue 5
,
pages 341-345
Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c
G B Guseva
1
,
Publication type: Journal Article
Publication date: 2007-05-25
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The thermodynamics of the reaction of cobalt(II) and zinc(II) acetates with 1,3,7,13,17,19-hexamethyl-2,8,12,18-tetrabutylbiladiene-a,c (H2L) in dimethylformamide (298.15 K) was studied by spectrophotometric and calorimetric titration. It was found that H2L and Zn(II) form a mononuclear porphyrine-like complex ZnL, and in the case of Co(II), a binuclear biligand complex Co2L2 with a doubly interlaced structure is formed. Thermodynamic characteristics of the formation of Co(II) and Zn(II) complexes with biladiene-a,c in DMF at 298.15 K were determined. In the template synthesis of macrocyclic compounds from H2L, it is more efficient to use Zn2+ than Co2+ ion as the template.
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Guseva G. B., Antina E. V. Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. Vol. 33. No. 5. pp. 341-345.
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Guseva G. B., Antina E. V. Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. Vol. 33. No. 5. pp. 341-345.
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TY - JOUR
DO - 10.1134/S1070328407050053
UR - https://doi.org/10.1134/S1070328407050053
TI - Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Guseva, G B
AU - Antina, E V
PY - 2007
DA - 2007/05/25
PB - Pleiades Publishing
SP - 341-345
IS - 5
VL - 33
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2007_Guseva,
author = {G B Guseva and E V Antina},
title = {Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2007},
volume = {33},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S1070328407050053},
number = {5},
pages = {341--345},
doi = {10.1134/S1070328407050053}
}
Cite this
MLA
Copy
Guseva, G. B., and E V Antina. “Thermodynamics of coordination interactions of cobalt(II) and zinc(II) acetates with hexamethyltetrabutyl-substituted biladiene-a,c.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 33, no. 5, May. 2007, pp. 341-345. https://doi.org/10.1134/S1070328407050053.
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