,
volume 33
,
issue 10
,
pages 734-740
Aggregates of the [GaCl4 ]- anion and the [Ga(H 2 O)3 (NCS)3 ] complex with 18C6
Publication type: Journal Article
Publication date: 2007-10-28
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The complex formation in the system GaCl3-ROH-MNCS-18K6 is considered (ROH = MeOH, EtOH; M = Na, K; 18C6 is 1,4,7,10,13,16-hexaoxocyclooctadecane). Two modifications of [Na(18C6)][GaCl4], namely, aggregates [Na(18C6)][GaCl4](MeOH)0.9(EtOH)1.1 and [Ga(H2O)3(NCS)3] · 18C6, are synthesized and identified. The 71Ga NMR (solutions) and X-ray diffraction studies showed that the compositions and structures of the title compounds are determined by the ratio of the competing acido ligands (Cl− and NCS−) in the reaction solution.
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Petrosyants S. P. et al. Aggregates of the [GaCl4]- anion and the [Ga(H 2O)3(NCS)3] complex with 18C6 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. Vol. 33. No. 10. pp. 734-740.
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Petrosyants S. P., Ilyukhin A. B. Aggregates of the [GaCl4]- anion and the [Ga(H 2O)3(NCS)3] complex with 18C6 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2007. Vol. 33. No. 10. pp. 734-740.
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RIS
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TY - JOUR
DO - 10.1134/S1070328407100041
UR - http://link.springer.com/10.1134/S1070328407100041
TI - Aggregates of the [GaCl4]- anion and the [Ga(H 2O)3(NCS)3] complex with 18C6
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Petrosyants, S P
AU - Ilyukhin, A. B.
PY - 2007
DA - 2007/10/28
PB - Pleiades Publishing
SP - 734-740
IS - 10
VL - 33
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Petrosyants,
author = {S P Petrosyants and A. B. Ilyukhin},
title = {Aggregates of the [GaCl4]- anion and the [Ga(H 2O)3(NCS)3] complex with 18C6},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2007},
volume = {33},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S1070328407100041},
number = {10},
pages = {734--740},
doi = {10.1134/S1070328407100041}
}
Cite this
MLA
Copy
Petrosyants, S. P., et al. “Aggregates of the [GaCl4]- anion and the [Ga(H 2O)3(NCS)3] complex with 18C6.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 33, no. 10, Oct. 2007, pp. 734-740. http://link.springer.com/10.1134/S1070328407100041.
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