Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 34, issue 8, pages 599-605
Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene
Publication type: Journal Article
Publication date: 2008-08-06
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The reactions of complex formation of Cu(II), Co(II), Zn(II), Ni(II), and Cd(II) acetates with 3,3′,4,4′5,5′-hexamethyl-2,2′-dipyrrolylmethene (HL) in DMF were studied by the electronic spectroscopy and calorimetric titration methods at 298.15 K. The main products of the above reactions are [ML2] chelates. In the case of Cu and Ni salts, the process occurs through the spectrally recorded stage of formation of the heteroligand [ML(AcO)] complexes. The reaction with Cd acetate terminates at the stage of the heteroligand complex formation due to the large radius and decreasing electron affinity of the Cd2+ ion. The effect of the metal nature appears in the increasing thermodynamic stability of single-type complexes in the series [ML2]: Ni(II) < Zn(II) < Co(II) < Cu(II) and [ML(AcO)]: Cd(II) < Ni(II) < Cu(II).
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Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya
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Citations by publishers
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Pleiades Publishing
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3 publications, 33.33%
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1 publication, 11.11%
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Springer Nature
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Springer Nature
1 publication, 11.11%
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Multidisciplinary Digital Publishing Institute (MDPI)
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1 publication, 11.11%
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Frontiers Media S.A.
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1 publication, 11.11%
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Wiley
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Wiley
1 publication, 11.11%
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Ivanovo State University of Chemistry and Technology
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Ivanovo State University of Chemistry and Technology
1 publication, 11.11%
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1
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3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Guseva G. B. et al. Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. Vol. 34. No. 8. pp. 599-605.
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Guseva G. B., Antina E. V., Vyugin A. I., Loginova A. E. Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. Vol. 34. No. 8. pp. 599-605.
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TY - JOUR
DO - 10.1134/S1070328408080071
UR - https://doi.org/10.1134%2FS1070328408080071
TI - Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Vyugin, A I
AU - Guseva, G B
AU - Antina, E V
AU - Loginova, A E
PY - 2008
DA - 2008/08/06 00:00:00
PB - Pleiades Publishing
SP - 599-605
IS - 8
VL - 34
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2008_Guseva,
author = {A I Vyugin and G B Guseva and E V Antina and A E Loginova},
title = {Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2008},
volume = {34},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS1070328408080071},
number = {8},
pages = {599--605},
doi = {10.1134/S1070328408080071}
}
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Guseva, G. B., et al. “Complex formation of Cu(II), Ni(II), Zn(II), Co(II), and Cd(II) acetates with 3,3′,4,4′,5,5′-hexamethyldipyrrolylmethene.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 34, no. 8, Aug. 2008, pp. 599-605. https://doi.org/10.1134%2FS1070328408080071.