,
volume 34
,
issue 11
,
pages 805-810
(Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2 Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl
Publication type: Journal Article
Publication date: 2008-10-31
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Electrophilic addition of PhTeI3 to phenylacetylene (PhC2H) in boiling THF stereoselectively gave (Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph (I). In a reaction with Fe(CO)5, this complex easily eliminated two iodine atoms from tellurium to give PhTe-CH=CPhI. This ligand was coordinated to iron in a monodentate fashion through the Te atom in the resulting complex (CO)3FeI2(PhTeHC=CPhI) (II). The reaction also yielded the known complex Fe(CO)4I2 (III). The structures of complexes I–III were determined by X-ray diffraction analysis. The Fe-Te bond in structure II is substantially shortened.
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11
Total citations:
11
Citations from 2024:
2
(18.18%)
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Torubaev Yu. V. et al. (Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. Vol. 34. No. 11. pp. 805-810.
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Torubaev Yu. V., Pasynskii A. A., MATHUR P. (Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2008. Vol. 34. No. 11. pp. 805-810.
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RIS
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TY - JOUR
DO - 10.1134/S1070328408110031
UR - http://link.springer.com/10.1134/S1070328408110031
TI - (Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Torubaev, Yu V
AU - Pasynskii, A A
AU - MATHUR, P.
PY - 2008
DA - 2008/10/31
PB - Pleiades Publishing
SP - 805-810
IS - 11
VL - 34
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2008_Torubaev,
author = {Yu V Torubaev and A A Pasynskii and P. MATHUR},
title = {(Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2008},
volume = {34},
publisher = {Pleiades Publishing},
month = {oct},
url = {http://link.springer.com/10.1134/S1070328408110031},
number = {11},
pages = {805--810},
doi = {10.1134/S1070328408110031}
}
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Torubaev, Yu. V., et al. “(Z)-diiodo(2-iodo-2-phenylvinyl)(phenyl)tellurium PhIC=CHTeI2Ph: Synthesis and complexing properties in a reaction with iron pentacarbonyl.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 34, no. 11, Oct. 2008, pp. 805-810. http://link.springer.com/10.1134/S1070328408110031.
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