том 35 издание 6 страницы 401-404

Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl

Тип публикацииJournal Article
Дата публикации2009-06-20
SCImago Q3
WOS Q4
БС2
SJR0.211
CiteScore1.6
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
A reaction of Cp′Mo(CO)3Cl(Cp′ = MeC5H4) with (PPh3)2Pt(C2Ph2) gave the heterometallic cluster Cp′Mo(μ-CO)2(C2Ph2)Pt2(PPh3)2(CO)Cl (I) as the sole product. According to X-ray diffraction data, complex I contains single Pt-Mo bonds (2.7962(5) and 2.7699(5) Å) but no Pt-Pt bond (Pt…Pt 2.9746(3) Å). The coordinated diphenylacetylene molecule forms two Pt-C σ-bonds (2.054(6) and 2.083(5) Å) and a π-bond to the Mo atom (Mo-C 2.265(6) and 2.272(5) Å; C≡C 1.387(8) Å).
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Coordination Chemistry Reviews
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Pasynskii A. A. et al. Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. Vol. 35. No. 6. pp. 401-404.
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Pasynskii A. A., Skabitskii I. V., Torubaev Yu. V., Shapovalov S. S. Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. Vol. 35. No. 6. pp. 401-404.
RIS |
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TY - JOUR
DO - 10.1134/S1070328409060025
UR - http://link.springer.com/10.1134/S1070328409060025
TI - Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Pasynskii, A A
AU - Skabitskii, I V
AU - Torubaev, Yu V
AU - Shapovalov, S S
PY - 2009
DA - 2009/06/20
PB - Pleiades Publishing
SP - 401-404
IS - 6
VL - 35
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2009_Pasynskii,
author = {A A Pasynskii and I V Skabitskii and Yu V Torubaev and S S Shapovalov},
title = {Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2009},
volume = {35},
publisher = {Pleiades Publishing},
month = {jun},
url = {http://link.springer.com/10.1134/S1070328409060025},
number = {6},
pages = {401--404},
doi = {10.1134/S1070328409060025}
}
MLA
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Pasynskii, A. A., et al. “Oxidative addition of the Mo-Cl bond to the Pt0 complex. Synthesis and structure of Cp?Mo(μ-CO)2(C2Ph 2)Pt2(PPh3)2(CO)Cl.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 35, no. 6, Jun. 2009, pp. 401-404. http://link.springer.com/10.1134/S1070328409060025.
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