,
volume 35
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issue 11
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pages 807-811
Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2 RuBr2 (PhTeBr)2 and (CO)3 Re(PhTeI) 3 (μ3-I): Synthesis and crystal and molecular structures
Publication type: Journal Article
Publication date: 2009-11-14
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Reactions of Ru3(CO)12 with PhTeBr3 and of Re(CO)5Cl with PhTeI in benzene give the stable complexes (CO)2RuBr2(PhTeBr)2 (I) and (CO)3Re(PhTeI)3(μ3-I) (II) containing two and three ligands PhTeX (X = Br or I), respectively. The bonds between these ligands and the central metal atom are fairly shortened (on average, Ru-Te, 2.608 Å; Re-Te, 2.7554(12)-2.7634(13) Å). The Te-X bonds in the ligands PhTeBr (2.5163(5) Å) and PhTeI (2.7893(15) Å) are not lengthened appreciably. In complex II, the iodide anion is not coordinated by rhenium, yet being attached through weak secondary bonds to three Te atoms of the three ligands PhTeI.
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Torubaev Yu. V. et al. Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2RuBr2(PhTeBr)2 and (CO)3Re(PhTeI) 3(μ3-I): Synthesis and crystal and molecular structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. Vol. 35. No. 11. pp. 807-811.
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Torubaev Yu. V., Pasynskii A. A., MATHUR P. Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2RuBr2(PhTeBr)2 and (CO)3Re(PhTeI) 3(μ3-I): Synthesis and crystal and molecular structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2009. Vol. 35. No. 11. pp. 807-811.
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TY - JOUR
DO - 10.1134/S1070328409110037
UR - http://link.springer.com/10.1134/S1070328409110037
TI - Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2RuBr2(PhTeBr)2 and (CO)3Re(PhTeI) 3(μ3-I): Synthesis and crystal and molecular structures
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Torubaev, Yu V
AU - Pasynskii, A A
AU - MATHUR, P.
PY - 2009
DA - 2009/11/14
PB - Pleiades Publishing
SP - 807-811
IS - 11
VL - 35
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2009_Torubaev,
author = {Yu V Torubaev and A A Pasynskii and P. MATHUR},
title = {Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2RuBr2(PhTeBr)2 and (CO)3Re(PhTeI) 3(μ3-I): Synthesis and crystal and molecular structures},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2009},
volume = {35},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S1070328409110037},
number = {11},
pages = {807--811},
doi = {10.1134/S1070328409110037}
}
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Torubaev, Yu. V., et al. “Phenyltellurenyl halide complexes of ruthenium and rhenium (CO) 2RuBr2(PhTeBr)2 and (CO)3Re(PhTeI) 3(μ3-I): Synthesis and crystal and molecular structures.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 35, no. 11, Nov. 2009, pp. 807-811. http://link.springer.com/10.1134/S1070328409110037.
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