,
volume 36
,
issue 11
,
pages 801-803
Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure
Publication type: Journal Article
Publication date: 2010-11-12
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Reduction of (PPh3)2PtCl2 with hydrazine hydrate in ethanol followed by treatment with an equivalent of an alkyne gave (butynediol)bis(triphenylphosphine)platinum(0), (PPh3)2Pt[C2(CH2OH)2] (I). According to X-ray diffraction data, the Pt atom in complex I has a square environment (Pt-C, 2.036(3) and 2.050(3) Å; Pt-P, 2.2719(8) and 2.2817(7) Å). In the coordinated butynediol, the C=C bond is lengthened(1.287(4) Å) and the angles C-C≡C are reduced to 140.3(3)° and 144.6(3)°, probably because of the donation of four electrons to the Pt atom. In the crystal, complex I forms dimers stabilized by hydrogen bonds between the hydroxy groups of adjacent molecules.
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Shapovalov S. S. et al. Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. Vol. 36. No. 11. pp. 801-803.
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Shapovalov S. S., Pasynskii A. A., Torubaev Yu. V. Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2010. Vol. 36. No. 11. pp. 801-803.
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TY - JOUR
DO - 10.1134/S1070328410110035
UR - http://link.springer.com/10.1134/S1070328410110035
TI - Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Pasynskii, A A
AU - Torubaev, Yu V
PY - 2010
DA - 2010/11/12
PB - Pleiades Publishing
SP - 801-803
IS - 11
VL - 36
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2010_Shapovalov,
author = {S S Shapovalov and A A Pasynskii and Yu V Torubaev},
title = {Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2010},
volume = {36},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S1070328410110035},
number = {11},
pages = {801--803},
doi = {10.1134/S1070328410110035}
}
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Shapovalov, S. S., et al. “Complex of bis(triphenylphosphine)platinum(0) with but-2-yne-1,4-diol: Synthesis and molecular structure.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 36, no. 11, Nov. 2010, pp. 801-803. http://link.springer.com/10.1134/S1070328410110035.