,
volume 39
,
issue 1
,
pages 33-36
Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds
A O Okhlobystin
1
,
I V Smolyaninov
1, 2
,
A V Okhlobystina
1
,
N T Berberova
1, 2
,
Yu Yu Koldaeva
1
,
V F Abdulaeva
1
Publication type: Journal Article
Publication date: 2012-12-29
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The chromium(III) tris-o-semiquinolate complex Cr(LSQ)3 (LSQ is 3,6-di-tert-butyl-o-semiquinone) and the monoanionic paramagnetic nickel(II) complex [n-Bu4N][Ni(L S SQ )(L S DT )] (L S SQ is o-thiosemiquinone, L S DT is benzene-1,2-dithiolate) are considered as electromediators of hydrogen sulfide oxidation in the presence of various organic substrates (hex-1-ene, oct-1-ene, benzene, toluene, and benzoic acid). It is revealed that the electrolysis of hydrogen sulfide at the oxidation potential of the mediators in the presence of the substrates affords the corresponding aliphatic and aromatic thiols in a yield of 62–75%.
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Total citations:
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Citations from 2024:
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Okhlobystin A. O. et al. Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2012. Vol. 39. No. 1. pp. 33-36.
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Okhlobystin A. O., Smolyaninov I. V., Okhlobystina A. V., Berberova N. T., Koldaeva Yu. Yu., Abdulaeva V. F. Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2012. Vol. 39. No. 1. pp. 33-36.
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RIS
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TY - JOUR
DO - 10.1134/S1070328413010077
UR - https://doi.org/10.1134/S1070328413010077
TI - Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Okhlobystin, A O
AU - Smolyaninov, I V
AU - Okhlobystina, A V
AU - Berberova, N T
AU - Koldaeva, Yu Yu
AU - Abdulaeva, V F
PY - 2012
DA - 2012/12/29
PB - Pleiades Publishing
SP - 33-36
IS - 1
VL - 39
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2012_Okhlobystin,
author = {A O Okhlobystin and I V Smolyaninov and A V Okhlobystina and N T Berberova and Yu Yu Koldaeva and V F Abdulaeva},
title = {Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2012},
volume = {39},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S1070328413010077},
number = {1},
pages = {33--36},
doi = {10.1134/S1070328413010077}
}
Cite this
MLA
Copy
Okhlobystin, A. O., et al. “Electromediators based on the Ni(II) and Cr(III) complexes with the redox-active ligands in the synthesis of sulfur-containing organic compounds.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 39, no. 1, Dec. 2012, pp. 33-36. https://doi.org/10.1134/S1070328413010077.
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