,
volume 39
,
issue 3
,
pages 229-233
Heterometallic cluster [CpMn(CO)2 ]2 S 2 Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand
Publication type: Journal Article
Publication date: 2013-03-05
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A reaction of the disulfide complex [CpMn(CO)2]2S2 with the Ni(0) diphosphine acetylene complex, (Dppe)Ni(C2Ph2) (I), yielded the heterometallic complex [CpMn(CO)2]2S2Ni(Dppe) (II). An X-ray diffraction study revealed lateral coordination of the disulfide group to the Ni atom in complex II, which results in lengthening of both the S-S and Mn-S bonds against those in the starting complex. However, the Mn-S and Ni-S bonds are still much shorter than the sums of the covalent radii of the corresponding atoms.
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Pasynskii A. A., Skabitskii I. V., Karpacheva M. V. Heterometallic cluster [CpMn(CO)2]2S 2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 3. pp. 229-233.
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Pasynskii A. A., Skabitskii I. V., Karpacheva M. V. Heterometallic cluster [CpMn(CO)2]2S 2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 3. pp. 229-233.
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TY - JOUR
DO - 10.1134/S1070328413030068
UR - https://doi.org/10.1134/S1070328413030068
TI - Heterometallic cluster [CpMn(CO)2]2S 2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Pasynskii, A A
AU - Skabitskii, I V
AU - Karpacheva, M V
PY - 2013
DA - 2013/03/05
PB - Pleiades Publishing
SP - 229-233
IS - 3
VL - 39
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors)
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@article{2013_Pasynskii,
author = {A A Pasynskii and I V Skabitskii and M V Karpacheva},
title = {Heterometallic cluster [CpMn(CO)2]2S 2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2013},
volume = {39},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S1070328413030068},
number = {3},
pages = {229--233},
doi = {10.1134/S1070328413030068}
}
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Pasynskii, A. A., et al. “Heterometallic cluster [CpMn(CO)2]2S 2Ni(Dppe) containing the binuclear manganese disulfide complex as a ligand.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 39, no. 3, Mar. 2013, pp. 229-233. https://doi.org/10.1134/S1070328413030068.
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