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том 39
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издание 7
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страницы 505-509
Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3 (H2 O)] · 3H2 O
Тип публикации: Journal Article
Дата публикации: 2013-07-04
scimago Q4
wos Q4
БС2
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Краткое описание
The binuclear tin(IV) complex with N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetic acid (H4Hedtra) is synthesized. The compound is characterized by elemental analysis, thermogravimetry, and IR spectroscopy. An X-ray diffraction analysis of complex Sn(μ-Hedtra)(μ-OH)SnCl3(H2O)] · 3H2O (I) is carried out. Structure I is formed by the binuclear complexes and molecules of water of crystallization. One of the tin atoms coordinates six “active” sites Hedtra4− (the alcohol branch is deprotonated and forms a bridge between two tin atoms) and the bridging hydroxo group. The polyhedron is a pentagonal bipyramid. The octahedral environment of the second tin atom is formed by two bridging oxygen atoms, three chlorine atoms (fac isomer), and a coordination water molecule.
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Martsinko E. É. et al. Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 7. pp. 505-509.
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Martsinko E. É., Ilyukhin A. B., Seifullina I. I., Chebanenko E. A., Sergienko V. S. Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 7. pp. 505-509.
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TY - JOUR
DO - 10.1134/S1070328413070075
UR - http://link.springer.com/10.1134/S1070328413070075
TI - Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Martsinko, E É
AU - Ilyukhin, A. B.
AU - Seifullina, I I
AU - Chebanenko, E A
AU - Sergienko, V S
PY - 2013
DA - 2013/07/04
PB - Pleiades Publishing
SP - 505-509
IS - 7
VL - 39
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2013_Martsinko,
author = {E É Martsinko and A. B. Ilyukhin and I I Seifullina and E A Chebanenko and V S Sergienko},
title = {Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2013},
volume = {39},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S1070328413070075},
number = {7},
pages = {505--509},
doi = {10.1134/S1070328413070075}
}
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Martsinko, E. É., et al. “Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 39, no. 7, Jul. 2013, pp. 505-509. http://link.springer.com/10.1134/S1070328413070075.