Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O

Publication typeJournal Article
Publication date2013-07-04
scimago Q4
wos Q4
SJR0.189
CiteScore1.7
Impact factor1.1
ISSN10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The binuclear tin(IV) complex with N-(2-hydroxyethyl)ethylenediamine-N,N′,N′-triacetic acid (H4Hedtra) is synthesized. The compound is characterized by elemental analysis, thermogravimetry, and IR spectroscopy. An X-ray diffraction analysis of complex Sn(μ-Hedtra)(μ-OH)SnCl3(H2O)] · 3H2O (I) is carried out. Structure I is formed by the binuclear complexes and molecules of water of crystallization. One of the tin atoms coordinates six “active” sites Hedtra4− (the alcohol branch is deprotonated and forms a bridge between two tin atoms) and the bridging hydroxo group. The polyhedron is a pentagonal bipyramid. The octahedral environment of the second tin atom is formed by two bridging oxygen atoms, three chlorine atoms (fac isomer), and a coordination water molecule.
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Martsinko E. É. et al. Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 7. pp. 505-509.
GOST all authors (up to 50) Copy
Martsinko E. É., Ilyukhin A. B., Seifullina I. I., Chebanenko E. A., Sergienko V. S. Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 7. pp. 505-509.
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TY - JOUR
DO - 10.1134/S1070328413070075
UR - http://link.springer.com/10.1134/S1070328413070075
TI - Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Martsinko, E É
AU - Ilyukhin, A. B.
AU - Seifullina, I I
AU - Chebanenko, E A
AU - Sergienko, V S
PY - 2013
DA - 2013/07/04
PB - Pleiades Publishing
SP - 505-509
IS - 7
VL - 39
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2013_Martsinko,
author = {E É Martsinko and A. B. Ilyukhin and I I Seifullina and E A Chebanenko and V S Sergienko},
title = {Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2013},
volume = {39},
publisher = {Pleiades Publishing},
month = {jul},
url = {http://link.springer.com/10.1134/S1070328413070075},
number = {7},
pages = {505--509},
doi = {10.1134/S1070328413070075}
}
MLA
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Martsinko, E. É., et al. “Synthesis, properties, and crystal structure of the tin(IV) complex with N-(2-hydroxyethyl)ethylenediaminetriacetic acid [Sn(μ-Hedtra)(μ-OH) SnCl3(H2O)] · 3H2O.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 39, no. 7, Jul. 2013, pp. 505-509. http://link.springer.com/10.1134/S1070328413070075.