Pleiades Publishing
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
,  volume 39 ,  issue 12 ,  pages 822-828

Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra

Publication type: Journal Article
Publication date: 2013-11-27
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Heating of the compounds (RC5H4)Fe(CO)2TePh (R = H (I) and Me (II)) in heptane afforded the dinuclear complexes [(RC5H4)Fe(CO)TePh]2 (III and IV, respectively). By oxidation with Fc+PF6−, these complexes were transformed into the paramagnetic cationic complexes [(RC5H4)Fe(CO)TePh]2PF6 (V and VI, respectively). Structures III–V and [(C5H5)Fe(CO)SPh]2PF6 (VII) were characterized by X-ray diffraction.
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Shapovalov S. S. et al. Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 12. pp. 822-828.
GOST all authors (up to 50) Copy
Shapovalov S. S., Pasynskii A. A., Skabitskii I. V., Sidorenkov A. S., Krishtop T. A., Minin V. V. Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2013. Vol. 39. No. 12. pp. 822-828.
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RIS Copy
TY - JOUR
DO - 10.1134/S1070328413120038
UR - https://doi.org/10.1134/S1070328413120038
TI - Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Pasynskii, A A
AU - Skabitskii, I V
AU - Sidorenkov, A S
AU - Krishtop, T A
AU - Minin, V V
PY - 2013
DA - 2013/11/27
PB - Pleiades Publishing
SP - 822-828
IS - 12
VL - 39
SN - 1070-3284
SN - 1608-3318
ER -
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BibTex (up to 50 authors) Copy
@article{2013_Shapovalov,
author = {S S Shapovalov and A A Pasynskii and I V Skabitskii and A S Sidorenkov and T A Krishtop and V V Minin},
title = {Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2013},
volume = {39},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S1070328413120038},
number = {12},
pages = {822--828},
doi = {10.1134/S1070328413120038}
}
MLA
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Shapovalov, S. S., et al. “Neutral and monocationic dinuclear (carbonyl)(cyclopentadienyl) (phenylchalcogenate) iron complexes of the general formulas [(RC 5H4)Fe(CO)EPh]2 and [(RC5H 4)Fe(CO)EPh]2PF6 (E = S or Te; R = H or Me): Synthesis, molecular structures, and EPR spectra.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 39, no. 12, Nov. 2013, pp. 822-828. https://doi.org/10.1134/S1070328413120038.