Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 40, issue 3, pages 131-137
Stannylene complexes of manganese, iron, and platinum
Shapovalov S S
1
,
Pasynskii A A
1
,
Torubaev Yu V
1
,
Skabitskii I V
1
,
SCHEER M.
2
,
Bodensteiner M
2
1
2
Institute of Inorganic Chemistry, Regensburg University, Regensburg, Germany
|
Publication type: Journal Article
Publication date: 2014-03-05
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor: 1.9
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A number of stannylene complexes with different M: Sn ratios were obtained using various metals and substituents at the tin atom. The structures of the complexes were examined. A reaction of CpMn(CO)2THF with (Ph4As)+(SnCl3)− gave the ionic complex [Ph4As]+[CpMn(CO)2SnCl3]− (I). The action of C6F5MgBr on the complex C5H5Mn(CO)(NO)SnCl3 produced C5H5Mn(CO)(NO)Sn(C6F5)3 (II). Replacement of the Cl ions in the complex [CpFe(CO)2]2SnCl2 by phenylacetylenide groups gave rise to the neutral complex [CpFe(CO)2]2Sn(C≡CPh)2 (III). A reaction of (Dppm)PtCl2 (Dppm is 1,1-bis(diphenylphosphino)methane) with SnCl2 · 2H2O in the presence of diglyme yielded the ionic complex [η3-CH3O(CH2)2O(CH2)2OCH3)SnCl]+[(η 2-Dppm)Pt(SnCl3)3]− (IV). Transmetalation in a reaction of [(Dppe)2CoCl][SnCl3] · PhBr (Dppe is 1,2-bis(diphenylphosphino)ethane) with (Dcpd)PtCl2 (Dcpd is dicyclopentadiene) in the presence of SnCl2 afforded the ionic complex [Pt(Dppe)2]3[Pt(SnCl3)5]2 (V). Structures I–V were identified by X-ray diffraction. In these structures, the formally single bonds between the atoms of transition metals M (Mn, Fe, and Pt) and Main Group heavy elements (Sn and P) having vacant d orbitals are appreciably shortened. The M-Sn bond length in complexes II and III are virtually independent of the substituents at the tin atom and the Pt-Sn bond length in complexes IV and V is virtually independent of the Pt: Sn ratio.
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Shapovalov S. S. et al. Stannylene complexes of manganese, iron, and platinum // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2014. Vol. 40. No. 3. pp. 131-137.
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Shapovalov S. S., Pasynskii A. A., Torubaev Yu. V., Skabitskii I. V., SCHEER M., Bodensteiner M. Stannylene complexes of manganese, iron, and platinum // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2014. Vol. 40. No. 3. pp. 131-137.
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TY - JOUR
DO - 10.1134/S1070328414030087
UR - https://doi.org/10.1134%2FS1070328414030087
TI - Stannylene complexes of manganese, iron, and platinum
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Shapovalov, S S
AU - Pasynskii, A A
AU - Torubaev, Yu V
AU - Skabitskii, I V
AU - SCHEER, M.
AU - Bodensteiner, M
PY - 2014
DA - 2014/03/05 00:00:00
PB - Pleiades Publishing
SP - 131-137
IS - 3
VL - 40
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2014_Shapovalov,
author = {S S Shapovalov and A A Pasynskii and Yu V Torubaev and I V Skabitskii and M. SCHEER and M Bodensteiner},
title = {Stannylene complexes of manganese, iron, and platinum},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2014},
volume = {40},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134%2FS1070328414030087},
number = {3},
pages = {131--137},
doi = {10.1134/S1070328414030087}
}
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Shapovalov, S. S., et al. “Stannylene complexes of manganese, iron, and platinum.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 40, no. 3, Mar. 2014, pp. 131-137. https://doi.org/10.1134%2FS1070328414030087.