,
volume 40
,
issue 9
,
pages 611-616
Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum
A A Pasynskii
1
,
Yu V Torubaev
1
,
A. V. Pavlova
1
,
S S Shapovalov
1
,
I V Skabitskii
1
,
G L Denisov
1
Publication type: Journal Article
Publication date: 2014-08-31
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A reaction of CpFe(CO)2TePh with Re(CO)3(THF)2Cl in THF gave the heterometallic complex [CpFe(CO)2(μ-TePh)]2Re(CO)3Cl (I). Either iron atom in complex I is linked to rhenium by only one Phenyltellurolate bridge. When treated with (Dppe)Pt(TePh)2, complex I underwent transmetalation by elimination of two CpFe(CO)2TePh molecules followed by the formation of the heterometallic chelate complex (Dppe)Pt(μ-TePh)2Re(CO)3Cl (II). Complex II was also obtained in an independent way from (Dppe)Pt(TePh)2 and Re(CO)3(THF)2. Structures I and II (II · MePh and II · CDCl3) were identified by X-ray diffraction (CIF file, CCDC nos. 981467, 981468, and 981469, respectively).
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Pasynskii A. A. et al. Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2014. Vol. 40. No. 9. pp. 611-616.
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Pasynskii A. A., Torubaev Yu. V., Pavlova A. V., Shapovalov S. S., Skabitskii I. V., Denisov G. L. Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2014. Vol. 40. No. 9. pp. 611-616.
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RIS
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TY - JOUR
DO - 10.1134/S1070328414090061
UR - http://link.springer.com/10.1134/S1070328414090061
TI - Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Pasynskii, A A
AU - Torubaev, Yu V
AU - Pavlova, A. V.
AU - Shapovalov, S S
AU - Skabitskii, I V
AU - Denisov, G L
PY - 2014
DA - 2014/08/31
PB - Pleiades Publishing
SP - 611-616
IS - 9
VL - 40
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Pasynskii,
author = {A A Pasynskii and Yu V Torubaev and A. V. Pavlova and S S Shapovalov and I V Skabitskii and G L Denisov},
title = {Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2014},
volume = {40},
publisher = {Pleiades Publishing},
month = {aug},
url = {http://link.springer.com/10.1134/S1070328414090061},
number = {9},
pages = {611--616},
doi = {10.1134/S1070328414090061}
}
Cite this
MLA
Copy
Pasynskii, A. A., et al. “Phenyltellurolate-bridged heterometallic complexes combining rhenium tricarbonyl with (dicarbonyl)(cyclopentadienyl)iron or bis(diphenylphosphino) ethaneplatinum.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 40, no. 9, Aug. 2014, pp. 611-616. http://link.springer.com/10.1134/S1070328414090061.