,
volume 41
,
issue 7
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pages 428-435
New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation
Publication type: Journal Article
Publication date: 2015-06-24
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
A series of new paramagnetic tin(IV) complexes based on sterically hindered o-iminobenzoquinones (R)ImQ differed in fragments (R) in the N-aryl fragment is synthesized. The thermal transformation of the tin(IV) complex, (iso-Pr)ImSQSn(tert-Bu)2Cl ((iso-Pr)ImSQ is the radical anion of 4,6-di-tert-butyl-N-(2,6-di-iso-propylphenyl)-o-iminobenzoquinone), is studied. The thermal transformation of the paramagnetic complex in nonane results in the formation of a new tin(II) bis(aminophenolate) derivative. The synthesized complexes and the thermolysis product are characterized by EPR, IR, and 1H, 13C, and 119Sn NMR spectroscopy and elemental analysis. The structures of the (tert-Bu)ImSQSn(tert-Bu)2Cl complex and the thermal decomposition product, {(iso-Pr)AmPh}2Sn ((iso-Pr)AmPh is 2-(2,6-di-iso-propylphenyl)amino-4,6-di-tert-butylphenolate), are determined by X-ray diffraction analysis.
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Total citations:
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Citations from 2025:
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(15.38%)
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Piskunov A. V. et al. New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 7. pp. 428-435.
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Piskunov A. V., Chegerev M. G., Vaganova L. B., Fukin G. K. New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2015. Vol. 41. No. 7. pp. 428-435.
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RIS
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TY - JOUR
DO - 10.1134/S1070328415070076
UR - https://doi.org/10.1134/S1070328415070076
TI - New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Piskunov, A. V.
AU - Chegerev, M G
AU - Vaganova, L B
AU - Fukin, G. K.
PY - 2015
DA - 2015/06/24
PB - Pleiades Publishing
SP - 428-435
IS - 7
VL - 41
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Piskunov,
author = {A. V. Piskunov and M G Chegerev and L B Vaganova and G. K. Fukin},
title = {New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2015},
volume = {41},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134/S1070328415070076},
number = {7},
pages = {428--435},
doi = {10.1134/S1070328415070076}
}
Cite this
MLA
Copy
Piskunov, A. V., et al. “New paramagnetic tin(IV) complexes based on o-iminoquinone ligands: Synthesis and thermal transformation.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 41, no. 7, Jun. 2015, pp. 428-435. https://doi.org/10.1134/S1070328415070076.