,
volume 42
,
issue 9
,
pages 574-583
The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals
Publication type: Journal Article
Publication date: 2016-09-15
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The formation of transition metal complexes with pivalate and cymantrenecarboxylate ligands in the presence of axial cyclopentadienyl and α-substituted pyridine ligands is discussed. The latter present steric hindrances due to repulsion from the O atoms of the carboxylate bridges. Particular emphasis is placed on the role of outer-sphere ammonium cations: their hydrogen bonding to fluoride bridges limits the growth of cyclic chromium(III) complexes with the pivalate and fluoride ligands that possess the properties of molecular magnets.
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Pasynskii A. A., Shapovalov S. S. The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2016. Vol. 42. No. 9. pp. 574-583.
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Pasynskii A. A., Shapovalov S. S. The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2016. Vol. 42. No. 9. pp. 574-583.
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RIS
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TY - JOUR
DO - 10.1134/S1070328416090050
UR - https://doi.org/10.1134/S1070328416090050
TI - The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Pasynskii, A A
AU - Shapovalov, S S
PY - 2016
DA - 2016/09/15
PB - Pleiades Publishing
SP - 574-583
IS - 9
VL - 42
SN - 1070-3284
SN - 1608-3318
ER -
Cite this
BibTex (up to 50 authors)
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@article{2016_Pasynskii,
author = {A A Pasynskii and S S Shapovalov},
title = {The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2016},
volume = {42},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/S1070328416090050},
number = {9},
pages = {574--583},
doi = {10.1134/S1070328416090050}
}
Cite this
MLA
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Pasynskii, A. A., and S S Shapovalov. “The role of inner- and outer-sphere ligands in pivalate and cymantrenecarboxylate complexes of transition metals.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 42, no. 9, Sep. 2016, pp. 574-583. https://doi.org/10.1134/S1070328416090050.
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