CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures

A A Pasynskii 1
, 
I V Skabitskiy 1
, 
Yu V Torubaev 1
, 
A. V. Pavlova 1
, 
S S Shapovalov 1
, 
O G Tikhonova 2
, 
S G Sakharov 1
1
 
2
 
Higher Chemical College of the Russian Academy of Sciences, Moscow, Russia | 
Publication type: Journal Article
Publication date: 2017-01-01
Pleiades Publishing
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
CpFe(CO)2TePh (I) can substitute one carbonyl group in Fe(CO)4I2 providing Fe(CO)3I2(μ-TePh)Fe(CO)2Cp (II) or play role of ligand to monomeric fragments [(p-Cymene)RuI2] and [Сp*RhI2] (p-Cymene = (η6-1-isopropyl-4-methylbenzene); Сp* = η5-pentamethylcyclopentadienyl) provides the complexes (p-Cymene)RuI2(μ-TePh)Fe(CO)2Cp (III) and Cp*RhCl2(μ-TePh)Fe(CO)2Cp (IV), respectively. The single-crystal X-ray diffraction of complexes II–IV (CIF files CCDC nos. 1038124 (II), 1038127 (III), 1038125 (IV)) revealed the shortening of М–Те bonds and the presence of intramolecular I…Te contacts.
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Pasynskii A. A. et al. CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 1. pp. 44-49.
GOST all authors (up to 50) Copy
Pasynskii A. A., Skabitskiy I. V., Torubaev Yu. V., Pavlova A. V., Shapovalov S. S., Tikhonova O. G., Sakharov S. G. CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2017. Vol. 43. No. 1. pp. 44-49.
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TY - JOUR
DO - 10.1134/S1070328417010067
UR - http://link.springer.com/10.1134/S1070328417010067
TI - CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Pasynskii, A A
AU - Skabitskiy, I V
AU - Torubaev, Yu V
AU - Pavlova, A. V.
AU - Shapovalov, S S
AU - Tikhonova, O G
AU - Sakharov, S G
PY - 2017
DA - 2017/01/01
PB - Pleiades Publishing
SP - 44-49
IS - 1
VL - 43
SN - 1070-3284
SN - 1608-3318
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2017_Pasynskii,
author = {A A Pasynskii and I V Skabitskiy and Yu V Torubaev and A. V. Pavlova and S S Shapovalov and O G Tikhonova and S G Sakharov},
title = {CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2017},
volume = {43},
publisher = {Pleiades Publishing},
month = {jan},
url = {http://link.springer.com/10.1134/S1070328417010067},
number = {1},
pages = {44--49},
doi = {10.1134/S1070328417010067}
}
MLA
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Pasynskii, A. A., et al. “CpFe(CO)2TePh as a ligand for organometallic dihalides Fe(CO)4I2, (p-Cymene)RuI2, and Me5C5RhI2: Synthesis and molecular structures.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 43, no. 1, Jan. 2017, pp. 44-49. http://link.springer.com/10.1134/S1070328417010067.